以甲胺为胶体化试剂,进而采用"层离-插层法"合成得到长链季铵盐十六烷基三甲基溴化铵(C16)/α-ZrP插层化合物(记为OZrP),并用XRD,TEM,SEM,IR等对其结构、形貌和疏水性等进行了表征和研究.结果显示,所获得的插层化合物OZrP保持有序的层状结构,层间距增大为2.9nm,并具有良好的疏水性,是制备聚合物/α-ZrP纳米复合材料的优良前驱物.
参考文献
| [1] | 耿利娜,相明辉,李娜,李克安.层状无机化合物--磷酸锆的研究和应用进展[J].化学进展,2004(05):717-727. |
| [2] | Ramos-Barrado J R;Martin F;Pérez-Reina F J et al.[J].Journal of Alloys and Compounds,1997,262-263:287. |
| [3] | Aránzazu Espina;Enrique Jaimez;Sergei A Khainakov et al.[J].Chemistry of Materials,1998,10:2490. |
| [4] | 张蕤,胡源,宋磊,朱玉瑞,范维澄,陈祖耀.层状化合物α-磷酸钛的水热合成与表征[J].稀有金属材料与工程,2001(05):384-387. |
| [5] | Takei T;Sekijima K;Wang D;Kumada N;Kinomura N .Soft chemical properties of layered zirconium hydroxy phosphate[J].Solid state ionics,2004(1/2):111-115. |
| [6] | Ding Y;Jones DJ;Maireles-Torres P et al.[J].Chemistry of Materials,1995,7(03):562. |
| [7] | Sue H J;Gam K T .[J].CHEMISTRY OF MATERIALS,2004,16(02):242. |
| [8] | Sue H J;Gam K T;Bestaoui N et al.[J].Acta Materialia,2004,52:2239. |
| [9] | Yoshitsugu H;Rieko M;Masahiko K et al.[J].Journal of Inclusion Phenomena and Macrocyclic Chemistry,2002,42:33. |
| [10] | Ludvik Benes;Klara Melanova;Vitezslav Zima;Pasquale Patrono;Paola Galli .Intercalation of Amino Alcohols into α-Zr(HPO_4)_2·H_2O[J].European journal of inorganic chemistry,2003(8):1577-1580. |
| [11] | David M Kaschak;Stacy A Johnson;Daniel E Hooks et al.[J].Journal of the American Chemical Society,1998,120(42):10887. |
| [12] | Olivera Pastor P;Maireles Torres P;Rodriguez Castellon E et al.[J].Chemistry of Materials,1996,8(08):1758. |
| [13] | 徐金锁.层状磷酸盐在有机胺溶液中的胶体化和稳定性研究[J].高等学校化学学报,1997(01):93. |
| [14] | Alexandre M;Dubois P .[J].Materials Science and Engineering,2000,28(01) |
| [15] | Wang J Z;Hu Y;Zhang R et al.[J].Journal of Crystal Growth,2004,263:377. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%