针对大直径直拉硅的微缺陷控制问题,模拟研究了初始氧浓度对于直径400 mm直拉硅单晶生长过程中原生点缺陷、空洞和氧沉淀演变规律.结果表明:晶体生长过程中氧沉淀和空洞的浓度及尺寸受晶体所经历的热历史和初始氧浓度的共同影响.当温度降低时,氧沉淀和空洞浓度降低,空洞尺寸增大,氧沉淀尺寸随初始氧浓度不同变化规律相异.在较低初始氧浓度时,随温度降低氧沉淀尺寸减小,在较高氧浓度时,氧沉淀尺寸增加.在相同热条件下,高温时,随初始氧浓度增加,空洞浓度先降低后升高,随后又继续降低;低温时,空洞浓度先不变后降低.
参考文献
[1] | 易晓剑.我国半导体硅材料工业现状及发展对策[J].湖南有色金属,2004(01):32-34. |
[2] | 徐岳生.直拉硅单晶生长的现状与发展[J].河北工业大学学报,2004(02):52-58. |
[3] | Scheel H J.The Development of Crystal Growth Technology in Crystal Growth Technology[M].New York:Scheel H J,Fukuda T,2003:1-14. |
[4] | 杨德仁,阙端麟.深亚微米集成电路用硅单晶材料[J].材料导报,2002(02):1-4,71. |
[5] | Voronkov V V;Falster R .Effect of Vacancies on Nucleation of Oxide Precipitates in Silicon[J].Materials Science in Semiconductor Processing,2003,5:387. |
[6] | T. Sinno;R. A. Brown;W. v. Ammon;E. Dornberger .Point defect dynamics and the oxidation-induced stacking-fault ring in Czochralski-grown silicon crystals[J].Journal of the Electrochemical Society,1998(1):302-318. |
[7] | Mori T .Modeling the Linkages between Heat Transfer and Microdefect Formation in Crystal Growth:Examples of Czochralski Growth of Silicon and Vertical Bridgman Growth of Bismuth Germinate[D].Massachusetts Institute of Technology,Massachusetts,2000. |
[8] | Milind S. Kulkarni .Defect dynamics in the presence of oxygen in growing Czochralski silicon crystals[J].Journal of Crystal Growth,2007(2):438-448. |
[9] | Kitamura K.;Furukawa J.;Nakada Y.;Ono N.;Shimanuki Y.;Eidenzon AM. Puzanov NI.;Puzanov DN. .Radial distribution of temperature gradients in growing CZ-Si crystals and its application to the prediction of microdefect distribution[J].Journal of Crystal Growth,2002(3/4):293-301. |
[10] | Xuegong Yu;Deren Yang;Xiangyang Ma;Duanlin Que .Effect of rapid thermal process on oxygen precipitation and denuded zone in nitrogen-doped silicon wafers[J].Microelectronic engineering,2003(1):97-104. |
[11] | 王宇鑫,邓文,严彪,董刚,李翔.直拉单晶硅太阳能电池光致衰减效应的正电子湮没谱研究[J].核技术,2010(05):346-349. |
[12] | 郝秋艳,刘彩池,孙卫忠,张建强,孙世龙,赵丽伟,张建峰,周旗钢,王敬.高温快速退火对重掺锑硅单晶中流动图形缺陷的影响[J].物理学报,2005(10):4863-4866. |
[13] | 王慧娟,陈成,邓联文,江建军.硅晶体中点缺陷结合过程的分子动力学模拟[J].材料科学与工程学报,2007(02):298-300. |
[14] | 乔永红,王绍青.Si晶体中空位运动的分子动力学研究[J].金属学报,2005(03):231-234. |
[15] | Domberger E;Tomzig E;Seidl A et al.Thermal Simulation of the Czochralski Silicon Growth Process by Three Gifferent Models and Comparison with Experimental Results[J].Journal of Crystal Growth,1997,180:461-467. |
[16] | Kashchiev D.Nucleation:Basic Theory with Applications[M].Oxford:Butterworth-Heinemann,2000 |
[17] | STR Group.CGSim Flow Module Theory Manual v.8.12[M].St.Petersburg,Russia:Richmond VA,2007 |
[18] | Wang Z H .Modeling Microdefects Formation in Crystaline Silicon:The Roles of Point Defects and Oxygen[D].Massachusetts Institute of Technology,2002. |
[19] | V. V. Voronkov;R. Falster .Intrinsic Point Defects and Impurities in Silicon Crystal Growth[J].Journal of the Electrochemical Society,2002(3):G167-G174. |
[20] | Newman R C;Jones R.Diffusion of Oxygen in Silicon in Semiconductors and Semimetals[M].SanDiego:F.Shimara,1994:289-352. |
[21] | Kato M;Yoshida T;Ikeda Y et al.Transmission Electron Microscope Observation of "IR Scattering Defects" in As-Grown Czochralski Si Crystals[J].Japanese Journal of Applied Physics,1996,35(11):5597-5601. |
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