采用电化学方法研究了6061铝合金在以CeCl3(0~60 mg/L)为添加剂的铬酸盐处理液中所得转化膜的防护性能.极化曲线测试结果表明,加入适量的CeCl3(20~40 mg/L),使电极的腐蚀电位Ecorr和点蚀电位Epit提高很多;电化学阻抗(EIS)测试结果表明,加入CeCl3后,膜层的阻抗大幅度增加.研究表明,加入适量的CeCl3可以有效改善膜层的防护性能,而过量的CeCl3(60 mg/L)却使其性能变差.
参考文献
[1] | Kendig M.;Addison R.;Waldrop J.;Jeanjaquet S. .Role of hexavalent chromium in the inhibition of corrosion of aluminum alloys[J].Surface & Coatings Technology,2001(1):58-66. |
[2] | Zhao J.;Sehgal A.;Lu D.;McCreery RL.;Frankel GS.;Xia L. .Effects of chromate and chromate conversion coatings on corrosion of aluminum alloy 2024-T3[J].Surface & Coatings Technology,2001(1):51-57. |
[3] | P.Campestrini;E.P.M.van Westing;J.H.W.de Wit .Influence of surface preparation on performance of chromate conversion coatings on Alclad 2024 aluminium alloy Part I: Nucleation and growth[J].Electrochimica Acta,2001(16):2553-2571. |
[4] | 余会成,陈白珍,石西昌,李兵,吴海鹰.6063铝合金三价铬化学转化膜的制备与电化学性能[J].物理化学学报,2008(08):1465-1470. |
[5] | Kulinich SA;Akhtar AS;Susac D;Wong PC;Wong KC;Mitchell KAR .On the growth of conversion chromate coatings on 2024-Al alloy[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(6):3144-3153. |
[6] | Hui-cheng Yu;Bai-zhen Chen;Xichang Shi;Xiliang Sun;Bin Li .Investigation of the trivalent-chrome coating on 6063 aluminum alloy[J].Materials Letters,2008(17/18):2828-2831. |
[7] | 朱利萍,鲁闯,熊仁章.铝合金稀土铈盐转化膜耐蚀性能研究[J].兵器材料科学与工程,2007(05):60-63. |
[8] | Woon -Jin Lee;Su-Il Pyun .Effects of sulphate ion additives on the pitting corrosion of pure aluminum in 0.01 M NaCl solution[J].Electrochimica Acta,2000(12):1901-1910. |
[9] | Yasakau KA;Zheludkevich ML;Lamaka SV;Ferreira MGS .Mechanism of corrosion inhibition of AA2024 by rare-earth compounds[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(11):5515-5528. |
[10] | KeunWoo Cho;V. Shankar Rao;HyukSang Kwon .Microstructure and electrochemical characterization of trivalent chromium based conversion coating on zinc[J].Electrochimica Acta,2007(13):4449-4456. |
[11] | Huicheng Yu;Baizhen Chen;Haiying Wu;Xiliang Sun;Bin Li .Improved electrochemical performance of trivalent-chrome coating on Al 6063 alloy via urea and thiourea addition[J].Electrochimica Acta,2008(2):720-726. |
[12] | 白丽群,舒康颖,郭敏,李荻.预处理对镁合金镧转化膜及耐腐蚀性能的影响[J].中国稀土学报,2008(05):592-597. |
[13] | 邝钜炽.稀土硝酸盐对磷化过程的促进作用[J].稀土,2006(01):80-82. |
[14] | 安茂忠,屠振密,杨哲龙,张景双,王家林.稀土化合物在磷化中的影响和作用[J].材料保护,2000(11):20-21,28. |
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