欢迎登录材料期刊网

材料期刊网

高级检索

橄榄石型LiFePO4正极材料具有原料来源丰富、无毒、环境友好、理论容量较高、热稳定性和循环性能好等特点,有望成为新一代锂离子电池正极材料.介绍了LiFePO4正极材料的结构、充放电机理、性能特点及存在的问题,综述了LiFePO4的合成工艺,添加导电材料和掺杂改性等方面的研究进展.

参考文献

[1] 詹晖,周运鸿.锂离子电池正极材料的发展[J].电源技术,1999(Z1):102.
[2] 陈立泉.锂离子电池正极材料的研究进展[J].电池,2002(z1):6-8.
[3] Padhi AK.;Goodenough JB.;Nanjundaswamy KS. .PHOSPHO-OLIVINES AS POSITIVE-ELECTRODE MATERIALS FOR RECHARGEABLE LITHIUM BATTERIES[J].Journal of the Electrochemical Society,1997(4):1188-1194.
[4] Padhi AK.;Masquelier C.;Okada S.;Goodenough JB.;Nanjundaswamy KS. .EFFECT OF STRUCTURE ON THE FE3+/FE2+ REDOX COUPLE IN IRON PHOSPHATES[J].Journal of the Electrochemical Society,1997(5):1609-1613.
[5] A. Yamada;S.C. Chung;K. Hinokuma .Optimized LiFePO_4 for Lithium Battery Cathodes[J].Journal of the Electrochemical Society,2001(3):A224-A229.
[6] Andersson A S;Thomas J O .The source of first-cycle capacity loss in LiFePO4[J].Journal of Power Sources,2001,97-98:498.
[7] Yang S F;Zavalij P Y;Whittingham M S .Hydrothermol synthesis of lithium iron phosphate cathodes[J].Electrochemistry Communications,2001,3:505.
[8] Chung S Y;Bloking J T;Chiang Y M .Electronically conductive phospho-olivines as lithium storage electrodes[J].Nature Materials,2002,1:123.
[9] Huang H;Yin S C;Nazar L F .Approaching theoretical capacity of LiFePO4 at room temperature at high rates[J].Electrochemical and Solid-State Letters,2001,4(10):170.
[10] Takahashi M;Tobishima S;Takei K et al.Characterization of LiFePO4 as the cathode material for rechargeable lithium batteries[J].Journal of Power Sources,2001,97-98:508.
[11] Prosini P P;Zane D;Pasquali M .Improved electrochemical performance of a LiFePO4-based composite cathode[J].Electrochimica Acta,2001,46:3517.
[12] Streltsov V A;Belokoneva E L;Tsirelson V G et al.Multipole analysis of the electron density in triphylite, LiFePO4, using X-ray diffraction data[J].Acta Crystallographica,1993,49:147.
[13] MacNeil D D;Lu Z H;Chen Z H et al.A comparison of electrode/electrolyte reaction at elevated temperatures for varies Li-ion battery cathode[J].Journal of Power Sources,2002,108(1-2):8.
[14] Park K S;SonJ T et al.Synthesis of LiFePO4 by co-precipitation and microwave heating[J].Electrochemistry Communications,2003,5:839.
[15] ARNOLD G;Garche J et al.Fine-particle lithium iron phosphate LiFePO4 synthesized by a new low-cost aqueous precipitation technique[J].Journal of Power Sources,2003,119-121:247.
[16] F. Croce;A.D' Epifanio;J. Hassoun .A Novel Concept for the Synthesis of an Improved LiFePO_4 Lithium Battery Cathode[J].Electrochemical and solid-state letters,2002(3):A47-A50.
[17] Zhaohui Chen;J. R. Dahn .Reducing Carbon in LiFePO_4/C Composite Electrodes to Maximize Specific Energy, Volumetric Energy, and Tap Density[J].Journal of the Electrochemical Society,2002(9):A1184-A1189.
[18] Park K S;Son J T;Chung H T et al.Surface modification by silver coating for improving electrochem properties of LiFePO4[J].Solid State Communications,2004,129:311.
[19] Atsuo Yamada;Yoshihiro Kudo;Kuang-Yu Liu .Reaction Mechanism of the Olivine-Type Li_x(Mn_(0.6)Fe_(0.4))PO_4 (0 <= x <= 1)[J].Journal of the Electrochemical Society,2001(7):A747-A754.
[20] Atsuo Yamada;Yoshihiro Kudo;Kuang-Yu Liu .Phase Diagram of Li_x(Mn_yFe_(1-y))PO_4 (0<=x, y<=1)[J].Journal of the Electrochemical Society,2001(10):A1153-A1158.
[21] Penazzia N;Arrabitoa M;Pianaa M et al.Mixed lithium phosphates as cathode materials for Li-ion cells[J].Journal of the European Ceramic Society,2004,24:1381.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%