整理了已公开发表的氢氟烃(HFC)/烷烃(HC)二元混合物气液相平衡实验数据,对实验数据进行了热力学一致性检验.采用PR方程加van der Waals混合规则描述该类混合物的气液相平衡性质,优化得到了11种混合物的二元交互作用系数,经比较表明采用优化结果能够高精度再现气液相平衡实验数据,比kij取0的计算结果有很大改善.
参考文献
| [1] | McLinden M O;Lemmon E W;Jacobsen R T .Thermodynamic Properties for the Alternative Refrigerants[J].International Journal of Refrigeration-Revue Internationale du Froid,1998,21(04):322-338. |
| [2] | 段远源,王忠伟.氢氟烃混合物气液相平衡研究进展[J].流体机械,2004(02):28-30,23. |
| [3] | Redlich O;Kister A T .Algebaric Representation of Thermodynamic Properties and the Classification of Solution[J].Industrial and Engineering Chemistry,1948,40(02):345-348. |
| [4] | Byer S M;Gibbs R E;Van Ness H C .Vapor-Liquid Equilibrium:Part Ⅰ.An Appraisal of Data Reduction Method[J].AICHE Journal,1973,19(02):238-244. |
| [5] | Renon H;Prausnitz J M .Local Compositions in Thermodynamic Excessfunctions for Liquid Mixtures[J].AIChE Journal,1967,14:135-144. |
| [6] | Kim JH.;Kim MS.;Kim Y. .Vapor-liquid equilibria for pentafluoroethane plus propane and difluoromethane plus propane systems over a temperature range from 253.15 to 323.15 K[J].Fluid Phase Equilibria,2003(2):273-287. |
| [7] | Jjong Sung Lim;Ji Young Park;Kab-Soo Lee .Measurement of Vapor-Liquid Equilibria for the Binary Mixture of Pentafluoroethane (HFC-125) + Propane (R-290)[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2004(4):750-755. |
| [8] | Park YM.;Jung MY. .Vapor-liquid equilibria for the pentafluoroethane (HFC-125) plus propane (R-290) system[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2002(4):818-822. |
| [9] | Peng D Y;Robinsion D B .A New Two-Constant Equation of State[J].Industrial and Engineering Chemistry Research,1976,15(01):59-64. |
| [10] | Lemmon E W;McLinden M O;Huber M L .Reference Fluid Thermodynamic and Transport Properties (REFPROP)[J].NIST Stand Re,2003,23(07) |
| [11] | Kleiber M .Vapor-Liquid Equilibria of Binary Refrigerant Mixtures Containing Propylene or R134a[J].Fluid Phase Equilibria,1994,92:149-194. |
| [12] | Stryjek R.;Camporese R.;Bobbo S. .Isothermal vapor-liquid equilibria for 1,1,1,2-tetrafluoroethane plus propane and propane plus 1,1,1-trifluoroethane at 283.18 K[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,1998(2):241-244. |
| [13] | Valtz A.;Coquelet C.;Baba-Ahmed A.;Richon D. .Vapor-liquid equilibrium data for the propane plus 1,1,1,2,3,3,3-heptafluoropropane (R227ea) system at temperatures from 293.16 to 353.18 K and pressures up to 3.4 MPa[J].Fluid Phase Equilibria,2002(1):29-47. |
| [14] | Bobbo S.;Artico G.;Fedele L.;Scattolini M.;Camporese R. .Vapor-liquid equilibrium measurements and correlation of the binary refrigerant mixture propane (HC-290)+1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) at 278.15, 293.15, and 308.15 K[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2002(4):839-842. |
| [15] | Higashi Y .Vapor-Liquid Equilibria for the Binary Difluoromethane (R-32)+Propane (R-290) Mixture[J].International Journal of Theoretical Physics,1999,20(02):507-518. |
| [16] | Bobbo S.;Fedele L.;Camporese R.;Stryjek R. .VLE measurements and modeling for the strongly positive azeotropic R32+propane system[J].Fluid Phase Equilibria,2002(1/2):175-183. |
| [17] | Christophe Coquelet;Albert Chareton;Alain Valtz;Abdelatif Baba-Ahmed;Dominique Richon .Vapor-Liquid Equilibrium Data for the Azeotropic Difluoromethane + Propane System at Temperatures from 294.83 to 343.26 K and Pressures up to 5.4 MPa[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2003(2):317-323. |
| [18] | Lee B G;Yang W J;Kim JD et al.Vapor-Liquid Equilibria for the Binary System Difluoromethane (Hfc-32)Plus Propane (HC-290) at Seven Temperatures[(268.15,278.15,283.15,288.15,298.15,308.15 and 318.15) K][J].Journal of Chemical and Engineering Data,2003,48(02):841-846. |
| [19] | Bobbo S.;Elvassore N.;Bertucco A.;Stryjek R. .A recirculation apparatus for vapor-liquid equilibrium measurements of refrigerants. Binary mixtures of R600a, R134a and R236fa[J].Fluid Phase Equilibria,1998(0):343-352. |
| [20] | Jong Sung Lim;Ji-Young Park;Byung-Gwon Lee;Youn-Woo Lee;Jae-Duck Kim .Phase Equilibria of CFC Alternative Refrigerant Mixtures: Binary Systems of Isobutane + 1,1,1,2-Tetrafluoroethane, + 1,1-Difluoroethane, and + Difluoromethane[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,1999(6):1226-1230. |
| [21] | Jihoon Im;Myungyoun Kim;Byung-Gwon Lee;Hwayong Kim .Vapor-Liquid Equilibria of the Binary n-Butane(HC-600)+Difluoromethane(HFC-32),+Pentafluoroethane(HFC-125),+1,1,1,2-Tetrafluoroethane(HFC-134a)Systems[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2005(2):359-363. |
| [22] | S. Shimawaki;K. Fujii .Vapor-Liquid Equilibria of HFC-32/n-Butane Mixtures[J].International Journal of Thermophysics,2003(4):1033-1042. |
| [23] | Fedele L;Bobbo S;Scattolini M;Camporese R;Stryjek R .Vapor-Liquid Equilibrium for the difluoromethane (R32)+n-butane (R600) system[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2005(1):44-48. |
| [24] | Wong D S H;Stanley S .A Theoretically Correct Mixing Rule for Cubic Equations of State[J].AICHE Journal,1992,38(05):671-680. |
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