通过共混法制备了含辣素衍生结构聚合物的抑菌性聚醚砜超滤膜.首先,用N-(5-甲基-3-异丁基-2羟基-苄基)-丙烯酰胺(MBHBA)和丙烯酸(AA)、甲基丙烯酸甲酯(MMA)制备了三元共聚物P(A-M-M),并通过红外光谱证实了聚合物的合成；然后考察了铸膜液中三元共聚物的质量浓度对所制备超滤膜性能的影响.结果表明,当P(A-M-M)质量分数为1％时,改性膜具有较高的综合性能:纯水通量和BSA截留率分别为183.8 L/(m2·h)和93.8％,与基膜相比略有提高；同时亲水性大幅增加,水静态接触角仅为57°,比基膜降低了17°；抑菌率达到了76％,远高于基膜的抑菌率(20％).
参考文献
| [1] | Drioli E;Giomo L.Comprehensive Membrane Science and Engineering[M].Italy:Elsevier Science,2010 |
| [2] | Rahimpour A;Madaeni S S;Mansourpanah Y .Nanoporous polyethersulfone (PES) membranes modified by acrylic acid (AA) and 2-hydroxyethylmethacrylate (HEMA) as additives in the gelation media[J].Journal of Membrane Science,2010,364(1/2):380-388. |
| [3] | ShenChong;Meng Qin;Zhang Guoliang .Chemical modification of polysulfone membrane by polyethylene glycol for resisting drug adsorption and self-assembly of hepatocytes[J].Journal of Membrane Science,2011,369(1/2):474-481. |
| [4] | Shi Qing;Su Yanlei;Ning Xue et al.Graft polymerization of methacrylic acid onto polyethersulfone for potential pH-responsive membrane materials[J].Journal of Membrane Science,2010,347(1/2):62-68. |
| [5] | Wei Xi;Wang Rong;Li Zhansheng;Anthony G. Fane .Development of a novel electrophoresis-UV grafting technique to modify PES UF membranes used for NOM removal[J].Journal of Membrane Science,2006(1/2):47-57. |
| [6] | Yune P S;Kilduff J E;Belfort G .Fouling-resistant properties of a surface-modified poly(ether sulfone) ultrafiltration membrane grafted with poly(ethylene glycol)-amide binary monomers[J].Journal of Membrane Science,2011,377:159-166. |
| [7] | Ahmad Rahimpour .UV photo-grafting of hydrophilic monomers onto the surface of nano-porous PES membranes for improving surface properties[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2011(1/3):93-101. |
| [8] | Wavhal DS.;Fisher ER. .Hydrophilic modification of polyethersulfone membranes by low temperature plasma-induced graft polymerization[J].Journal of Membrane Science,2002(1):255-269. |
| [9] | Cen L.;Neoh KG.;Kang ET. .Surface functionalization technique for conferring antibacterial properties to polymeric and cellulosic surfaces[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(24):10295-10303. |
| [10] | Shi Z;Neoh KG;Kang ET .Antibacterial activity of polymeric substrate with surface grafted viologen moieties.[J].Biomaterials,2005(5):501-508. |
| [11] | Sui Yan;Gao Xueli;Wang Zhining et al.Antifouling and antibacterial improvement of surface-functionalized poly(vinylidene fluoride)membrane prepared via dihydroxyphenylalanine-initiated atom transfer radical graft polymerizations[J].Journal of Membrane Science,2012,394-395:107-119. |
| [12] | 徐焕志,于良民,李昌诚,张志明.辣素衍生物的合成及其对新月菱形藻生长的抑制活性[J].应用化学,2007(08):911-916. |
| [13] | 徐焕志 .含辣素衍生结构的丙烯酰胺单体与聚合物的合成及其海洋防污应用性能研究[D].中国海洋大学,2006. |
| [14] | 于良民 .环境友好型丙烯酸树脂的合成及其在海洋防污涂料中的应用研究[D].中国海洋大学,2004. |
| [15] | 时钧;袁权;高从堦.膜技术手册[M].北京:化学工业出版社,2001 |
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