利用极化曲线、电化学阻抗谱(EIS)研究了三聚磷酸钠和苯乙烯膦酸钠及其复合后对Q235碳钢在3% NaCl溶液中的缓蚀性能.结果表明:苯乙烯膦酸钠为混合型缓蚀剂,对钢的阴、阳极腐蚀反应都有明显的抑制;磷酸盐复合盐对Q235碳钢有更好的缓蚀作用;2种磷酸盐在碳钢表面存在竞争性吸附,导致较小的协同效应,不利于保护膜的生成;两者浓度均为8 mmol/L时,缓蚀效率最大,可达82%.
参考文献
[1] | Edwards M;Hidmi L;Gladwell D .Phosphate inhibition of soluble copper corrosion by-product release[J].Corrosion Science,2002,44(05):1057-1071. |
[2] | Etteyeb N;Dhouibi L;Takenouti H et al.Corrosion inhibition of carbonsteel in alkaline chloride media by Na3 PO4[J].Electrochimica Acta,2007,52(27):7506-7512. |
[3] | Y. W. Song;D. Y. Shan;E. H. Han .Corrosion behaviors of electroless plating Ni-P coatings deposited on magnesium alloys in artificial sweat solution[J].Electrochimica Acta,2007(4):2009-2015. |
[4] | 艾仕云 .有机膦酸盐缓蚀阻垢剂的研究和发展[J].化学清洗,1997,13(02):27-30. |
[5] | 赵丽娜,许淳淳.无机复合缓蚀剂对碳钢的缓蚀性能[J].腐蚀与防护,2008(08):460-463. |
[6] | M. Behpour;S.M. Ghoreishi;N. Soltani;M. Salavati-Niasari .The inhibitive effect of some bis-N,S-bidentate Schiff bases on corrosion behaviour of 304 stainless steel in hydrochloric acid solution[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2009(5):1073-1082. |
[7] | Achouri M E;Kertit S;Gouttaya H M et al.Corrosion inhibition of iron in 1 M HC1 by some gemini surfactants in the series of alkanediyl-α,ω-bis-(dimethyl tetradecyl ammonium bromide)[J].Progress in organic Coatings,2001,43(04):267-273. |
[8] | 王佳;曹楚南;陈家坚 .缓蚀剂阳极脱附现象的研究Ⅰ.缓蚀剂阳极脱附现象[J].中国腐蚀与防护学报,1995,15(04):241-246. |
[9] | Franklin M J;White D C;Isaacs H S .A study of carbon steel corrosion inhibition by phosphate ions and by an organic buffer using a scanning vibrating electrode[J].Corrosion Science,1992,33(02):251-260. |
[10] | Solmaza R;Altunbas E;Kardas G .Adsorption and corrosion inhibition effect of 2-((5-mercapto-1,3,4-thiadiazol-2-ylimino) methyl) phenol Schiff base on mild steel[J].Materials Chemistry and Physics,2011,125(03):796-801. |
[11] | Bayol E;Kayakirilmaz K;Erbil M .The inhibitive effect of hexamethylenetetramine on the acid corrosion of steel[J].Materials Chemistry and Physics,2007(1):74-82. |
[12] | A. Paszternak;S. Stichleutner;I. Felhosi;Z. Keresztes;F. Nagy;E. Kuzmann;A. Vertes;Z. Homonnay;G. Peto;E. Kalman .Surface modification of passive iron by alkyl-phosphonic acid layers[J].Electrochimica Acta,2007(2):337-345. |
[13] | Omar A H .Corrosion inhibition studies of copper in highly concentrated NaC1 solutions[J].Journal of Applied Electrochemistry,2007,37(08):933-940. |
[14] | Ma H;Cheng X L;Li G et al.The influence of hydrogen sulfide on corrosion of iron under different conditions[J].Corrosion Science,2000,42(10):1669-1683. |
[15] | Lorenz W J;Mansfeld F .Determination of corrosion rates by electrochemical DC and AC methods[J].Corrosion Science,1981,21(9/10):647-672. |
[16] | Aramaki K;Hackerman N .Inhibition mechanism of medium-sized polymethyleneimine[J].Journal of the Electrochemical Society,1969,116(05):568-574. |
[17] | Pavithra M K;Venkatesha T V;Vathsala K et al.Synergistic effect of halide ions on improving corrosion inhibition behavior of benzisothiozole-3-piperizine hydrochloride on mild steel in 0.5 M H2SO4 medium[J].Corrosion Science,2010,52(11):3811-3819. |
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