采用单体聚合法以FeCl3为引发剂进行噻吩的聚合反应,得到了导电性好的γ-Fe2O3/聚噻吩纳米复合材料.红外、透射电镜、穆斯堡尔谱等研究表明γ-Fe2O3与聚噻吩之间有着一定的相互作用.复合材料的导电性明显高于纯的聚噻吩样品,随着γ-Fe2O3含量的增加,复合材料的导电性呈增大趋势.
参考文献
[1] | 殷华茹,姜继森.纳米氧化铁-聚合物复合材料的研究进展[J].材料导报,2003(z1):121-124. |
[2] | Chen AH.;Wang HQ.;Zhao B.;Li XY. .Preparation of polypyrrole-Fe3O4 nanocomposites by the use of common ion effect[J].Synthetic Metals,2003(2):411-415. |
[3] | Liu J.;Wan MX. .Composites of polypyrrole with conducting and ferromagnetic behaviors[J].Journal of Polymer Science, Part A. Polymer Chemistry,2000(15):2734-2739. |
[4] | Gangopadhyay R P;Amitabha D .[J].European Polymer Journal,1999,35(11):1985-1992. |
[5] | Yan F;Xue G;Chen J .[J].Synthetic Metals,2001,123(01):1985-1992. |
[6] | Zhang Z M;Wan M X .[J].Synthetic Metals,2003,132(02):205-212. |
[7] | Kryszewski M.;Jeszka JK. .Nanostructured conducting polymer composites - superparamagnetic particles in conducting polymers[J].Synthetic Metals,1998(1):99-104. |
[8] | Chen TA.;Rieke RD.;Wu XM. .REGIOCONTROLLED SYNTHESIS OF POLY(3-ALKYLTHIOPHENES) MEDIATED BY RIEKE ZINC - THEIR CHARACTERIZATION AND SOLID-STATE PROPERTIES[J].Journal of the American Chemical Society,1995(1):233-244. |
[9] | Faid K.;Nguyen M.;Diaz A.;Leclerc M. .LOCALIZATION EFFECTS IN ASYMMETRICALLY SUBSTITUTED POLYTHIOPHENES - CONTROLLED GENERATION OF POLARONS, DIMERIZED POLARONS, AND BIPOLARONS[J].Macromolecules,1995(1):284-287. |
[10] | Yoshizumi M .[J].Silicates Industries,1984,7-8(01):151-157. |
[11] | 曹镛;过丁;叶成 等.[J].化学学报,1987,45:1072-1076. |
[12] | 董绍俊;张文斌 .[J].应用化学,1991,8(01):50-54. |
[13] | McDevitt N T;Baun W L .[J].Spectrochimica Acta,1964,20(04):799-808. |
[14] | Armour M;Dvaies A G;Upadhyay J et al.[J].Journal of Polymer Science Part A:Polymer Chemistry,1967,5(10):1527-1538. |
[15] | Peter K;Kathryn V;Mcfarland N .[J].Journal of Polymer Science Part A:Polymer Chemistry,1979,17(07):1963-1976. |
[16] | 姜国华,姜继森.γ-Fe2O3纳米粒子的(湿)固相研磨法制备研究[J].高等学校化学学报,2004(03):405-408. |
[17] | 姜继森,高濂,杨燮龙,郭景坤.α-Fe2O3纳米微粒的制备及其M(o)ssbauer谱研究[J].物理化学学报,2000(04):312-316. |
[18] | 马如璋;吴兵;李玉璞.穆斯堡尔谱学手册[M].北京:冶金工业出版社,1993:339. |
[19] | Xu JM.;Chan HSO.;Ng SC.;Chung TS. .Polymers synthesized from (3-alkylthio)thiophenes by the FeCl3 oxidation method[J].Synthetic Metals,2002(1):63-69. |
[20] | 张光敏,阎康平.本征导电高分子材料的进展[J].电子元件与材料,1999(04):41-42. |
[21] | Bidan G;Jarjayes O;Fruhart J M et al.[J].Advanced Materials,1994,6(02):152-155. |
[22] | QIAN Xin-ming,ZHANG Xin-tong,SHAO Hui-bo,BAI Yu-Bai,LI Tie-jin,TANG Xin-yi,DONG Shao-Jun.UV-Vis and Surface Photovoltage Spectra of Fe2O3/Polystyrene Composite Microspheres[J].高等学校化学研究(英文版),2002(01):75-78. |
[23] | Du H;Zhang P;Liu F Q et al.[J].Polymer International,1997,43(03):274-280. |
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