采用新型二烷氧基型硅烷偶联剂及传统三烷氧基型硅烷偶联剂对苯丙乳液进行改性,通过电化学阻抗方法对改性前后涂膜的防腐性能进行研究.结果表明,改性涂膜的防腐性能优于未改性涂膜,而新型二烷氧基型硅烷偶联剂KH-578改性苯丙乳液的防腐性能最佳.
The styrene-acrylic emulsion was modified by a new bis-alkoxyl silane coupling agent and a conventional trialkoxyl silane coupling agent. The corrosion protection property of the coating before and after modification was studied by electrochemical impedance spectroscopy (EIS). The results showed that the corrosion protection property of the modified coating is better than that of the unmodified coating, and the corrosion protection performance of the styrene acrylic emulsion modified by the new bisalkoxyl silane coupling agent KH-578 is the best.
参考文献
| [1] | 余远斌;张燕慧.苯丙乳液研究进展[J].化工进展,1996(02):36-39. |
| [2] | 刘平平,程江,文秀芳,皮丕辉,杨卓如.水性防腐涂料用苯丙乳液的研究进展[J].涂料工业,2005(07):53-56. |
| [3] | 张颖怀,许立宁,路民旭,张璞.用电化学阻抗谱（EIS）研究环氧树脂涂层的防腐蚀性能[J].腐蚀与防护,2007(05):227-230,234. |
| [4] | CHEN Y;HONG T;GOPAL M et al.EIS Studies of a corrosion inhibitor behavior under multiphase flow conditions[J].Corrosion Science,2000,42(06):979-990. |
| [5] | 刘斌,李瑛,林海潮,曹楚南.丙烯酸聚氨酯涂料防腐蚀性能研究[J].中国腐蚀与防护学报,2003(02):89-91,98. |
| [6] | 张智,熊金平,曹京宜,左禹.不同表面处理等级下有机涂层失效行为的EIS研究[J].新技术新工艺,2008(10):90-93. |
| [7] | 曹楚南;张鉴清.电化学阻抗谱导论[M].北京:科学出版社,2002:154-165. |
| [8] | MCINTYRE J M;PHAM H Q .Electrochemical impedance spectroscopy:a tool for organic coatings optimizations[J].Progress in Organic Coatings,1996,27(1/4):201-207. |
| [9] | 李玮,左禹,熊金平,曹京宜.不同表面处理条件下复合涂层体系失效过程的EIS特征[J].化工学报,2008(02):420-425. |
| [10] | 王燕.金属防锈乳胶的研究[J].材料保护,2001(01):33-34. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%