在Ni镀液中添加2g/L、4g/L的-400目的Ti粉,获取Ni-7.8at%Ti、Ni-35at%Ti镀层,并对所制备的镀层进行了结构和析氢性能分析.结果表明:随着镀液中Ti粉的添加,镀层中Ti含量增加,镀层结构呈现多孔性,镀层的表面积得到大幅度提升.在25℃、6mol/L的NaOH溶液中的电解析氢实验表明:Ni-Ti镀层电极比Ni镀层电极具有更好的析氢性能,且析氢性能随着Ni-Ti镀层中Ti含量的增加而增强;长时间浸泡之后的电解析氢表明Ni-Ti镀层电极在碱性溶液中有良好的稳定性.
参考文献
[1] | B. Karbakhsh Ravari;S. Farjami;M. Nishida.Effects of Ni concentration and aging conditions on multistage martensitic transformation in aged Ni-rich Ti-Ni alloys[J].Acta materialia,2014:17-29. |
[2] | Talal A. Aljohani;Brian E. Hayden.A simultaneous screening of the corrosion resistance of Ni-W thin film alloys[J].Electrochimica Acta,2013:930-936. |
[3] | 韩朝,刘咏,王岩,李维杰,汤慧萍.Ni-xCr-6.8Al基合金热腐蚀行为[J].中国有色金属学报(英文版),2011(11):2348-2357. |
[4] | A. Krolikowski;A. Wiecko .Impedance studies of hydrogen evolution on Ni-P alloys[J].Electrochimica Acta,2002(13/14):2065-2069. |
[5] | 李瑞,胡泽忠,刘永锋,高明霞,潘洪革.La0.7Mg0.3Ni2.65Co0.75-xMn0.1Six储氢电极合金的结构和电化学性能[J].材料科学与工程学报,2013(03):372-375,460. |
[6] | Liang Wu;Yuehui He;Ting Lei;Bo Nan;Nanping Xu;Jin Zou;Baiyun Huang;C.T. Liu .Characterization of porous Ni_3Al electrode for hydrogen evolution in strong alkali solution[J].Materials Chemistry and Physics,2013(1):553-561. |
[7] | C. Gonzdlez-Buch;I. Herraiz-Cardona;E. Ortega;J. Garcia-Anton;V. Perez-Herranz .Synthesis and characterization of macroporous Ni, Co and Ni-Co electrocatalytic deposits for hydrogen evolution reaction in alkaline media[J].International journal of hydrogen energy,2013(25):10157-10169. |
[8] | Youjun Xu;Yongyong Zhu;Guorong Xiao .Application of artificial neural networks to predict corrosion behavior of Ni-SiC composite coatings deposited by ultrasonic electrodeposition[J].CERAMICS INTERNATIONAL,2014(4):5425-5430. |
[9] | Susan DF.;Marder AR.;Barmak K. .ELECTRODEPOSITED NI-AL PARTICLE COMPOSITE COATINGS[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1997(1/2):133-140. |
[10] | J. Kubisztal;A. Budniok;A. Lasia .Study of the hydrogen evolution reaction on nickel-based composite coatings containing molybdenum powder[J].International journal of hydrogen energy,2007(9):1211-1218. |
[11] | 陈劲松,黄因慧,田宗军,刘志东,贺毅强.喷射电沉积Ni-Al2O3纳米复合镀层的组织及性能[J].材料科学与工程学报,2010(06):912-915,929. |
[12] | Han-Ho Lee;Ki-Young Lee;Jai-Young Lee .[J].Journal of Alloys and Compounds,1996,239(1):63-70. |
[13] | Makoto Tsukahara;Kunio Takahashi et al.[J].Journal of Alloys and Compounds,1995,224(1):162-167. |
[14] | M Tsukahara;K Takahashi et al.Metal hydride electrodes based on solid solution type alloy TiV3Nix(0≤x≤0.75)[J].Journal of Alloys and Compounds,1995,226(1-2):203-207. |
[15] | N V Krstaji c;B N Grgur et al.The determination of kinetics parameters of the hydrogen evolution on Ti-Ni alloys by ac impedance[J].Electrochimica Acta,1997,42(2):323-330. |
[16] | T. Sonoda;A. Watazu;J. Zhu;W. Shi;K. Kato;T. Asahina .Structure and mechanical properties of pure titanium film deposited onto TiNi shape memory alloy substrate by magnetron DC sputtering[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2004(1/2):212-215. |
[17] | J Y Xiong,Y C Li,P D Hodgson,C E Wen.TiNi Shape Memory Alloy Foams Synthesized by Spacer Sintering and their Properties[J].材料科学与工程学报,2007(06):892-894,898. |
[18] | Hongxing Dong;Ting Lei;Yuehui He;Nanping Xu;Baiyun Huang;C.T. Liu .Electrochemical performance of porous Ni_3Al electrodes for hydrogen evolution reaction[J].International journal of hydrogen energy,2011(19):12112-12120. |
[19] | Po-Chun Chen;Yun-Min Chang;Pu-Wei Wu;Yu-Fan Chin .Fabrication of Ni nanowires for hydrogen evolution reaction in a neutral electrolyte[J].International journal of hydrogen energy,2009(16):6596-6602. |
[20] | Gü lfeza Kardas Ramazan Solmaz .Hydrogen evolution and corrosion performance of NiZn coatings[J].Energy Conversion & Management,2007,48:583-591. |
[21] | Wang Liping;Zhang Junyan et al.Grain size effect in corrosion behavior of electrodeposited nanocrystalline Ni coatings in alkaline solutions[J].Scripta Materialia,2006,55:657-660. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%