The segregation of carbon at grain boundaries and its effect on phosphorus segregation and phosphorus-induced intergranular fracture in the alloy of high purity iron with phosphorus were investigated by scanning Auger electron spectroscopy, impact test and SEM observation of fractured surface. The experimental results showed that the carbon segregation at grain boundaries decreases the phosphorus segregation, and a change of fracture mode from intergranular fracture to transgranular one, hence a decrease of ductile-brittle transition temperature is observed. The mechanism of these effects was discussed.
参考文献
[1] | Erhart H;Grabke H J .Equilibrium Segregation of Phosphorus at Grain Boundaries of Fe-P, Fe-C-P, Fe-Cr-P and Fe-Cr-C-P Alloys[J].Metal Science Journal,1981,15(09):401-408. |
[2] | Suzuki S;Abiko K;Kimura H .Phosphorus Segregation Related to the Grain Boundary Structure in an Fe-P Alloy[J].Scripta Metallurgica et Materialia,1981,15(10):1139-1143. |
[3] | Suzuki S;Obata M;Abiko K et al.Prevention of the Intergranular Fracture in Iron-Phosphorus Alloys[J].Iron and Steel,1984,70(16):2262-2268. |
[4] | Abiko K;Suzuki S;Kimura H .Chemical State of Phosphorus Segregated at Grain Boundaries of Iron[J].Iron and Steel,1983,69(06):625-630. |
[5] | Liu C M;Abiko K;Kimura H .Prevention of the Intergranular Fracture by Addition of Silicon and Aluminum to a High-Purity Fe-0.2 %P Alloy with a Trace of Boron[J].Metallurgical and Materials Transactions,1992,23(05):1515-1519. |
[6] | Mega T;Shimomura J;Seto K .Grain Boundary Segregation of Phosphorus, Boron and Manganese in High Strength Steel Sheet[J].Materials Transactions,1996,37(03):323-329. |
[7] | S.-H. Song;R. G. Faulkner .Effect of boron on phosphorus-induced temper embrittlement[J].Journal of Materials Science,1999(22):5549-5556. |
[8] | Tetsuya Mega;Jun-ichi Shimomura;Eiko Yasuhara .Grain Boundary Segregation of Phosphorus and Boron in Extra-Low Carbon Steels[J].Materials Transactions, JIM,1995(10):1206-1213. |
[9] | Oku M;Suzuki S;Abiko K et al.Study of Chemical States at Intergranular Fracture Planes of Iron-Phosphorus Alloys by Auger and Electron Energy-Loss Spectroscopes[J].Journal of Electron Spectroscopy and Related Phenomena,1984,34(01):55-65. |
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