尖晶石LiMn2O4的掺杂研究进展

材料导报, 2003, 17(6): 44-76.

尖晶石LiMn2O4的掺杂研究进展

刘烈炜 ^1, , 田炜 ^2, , 赵新强 ^3, , 赵志祥 ^4,

1.华中科技大学化学系,武汉,430074

2.华中科技大学化学系,武汉,430074

3.华中科技大学化学系,武汉,430074

4.华中科技大学化学系,武汉,430074

关键词：掺杂 , LiMn2O4 , 尖晶石 , 进展

Progress in Research on Doped Spinel LiMn2O4

相对LiCoO2来说,价廉、低毒的尖晶石LiMn2O4作为高能锂离子电池最有潜力的正极材料已经成为市场研究的热点.但是,在充放电过程中其结构的不稳定制约了它的应用前景.为了得到结构稳定的尖晶石,许多研究小组通过掺杂其它元素来改性LiMn2O4.综述了近几年来在这方面的研究进展.

参考文献

[1]	Tarascon j M;Mckinnon W R;Coowar F et al.[J].Journal of the Electrochemical Society,1994,141(06):1421.
[2]	Liu W.;Chaput F.;Dunn B.;Farrington GC. .SYNTHESIS AND ELECTROCHEMICAL STUDIES OF SPINEL PHASE LIMN2O4 CATHODE MATERIALS PREPARED BY THE PECHINI PROCESS[J].Journal of the Electrochemical Society,1996(3):879-884.
[3]	Peramunage D;Abraham K M .[J].Journal of the Electrochemical Society,1998,145(04):1131.
[4]	Marzec J.;Swierczek K.;Przewoznik J.;Molenda J.;Simon DR.;Kelder EM. Schoonman J. .Conduction mechanism in operating a LiMn2O4 cathode[J].Solid state ionics,2002(3/4):225-237.
[5]	Thackeray M M;Mansuetto M F;Bates J Bries .[J].Journal of Power Sources,1997,68:153.
[6]	Sato K;Poojary D M;Clearfild A .[J].Journal of Solid State Chemistry,1997,131:84.
[7]	Li Guohua;Lkuta H;Uchids T et al.[J].Journal of the Electrochemical Society,1996,143(01):178.
[8]	Liu Zhaolin;Yu Aishui;Lee J Y .[J].Journal of Power Sources,1998,74:228.
[9]	Choi Heon Jin;Lee Ki Min;Lee June Gunn .[J].Journal of Power Sources,2001,103:154.
[10]	Amarilla JM.;Rojas RM.;de Vidales JLM. .Electrochemical characteristics of cobalt-doped LiCoyMn2-yO4 (0 <= y <= 0.66) spinels synthesized at low temperature from CoxMn3-xO4 precursors[J].Solid state ionics,2000(1/2):73-81.
[11]	Arira P;Popov B N;White R E .[J].Journal of the Electrochemical Society,1998,145(03):807.
[12]	Sigala C.;Verbaere A.;Piffard Y.;Tournoux M.;Guyomard D. .POSITIVE ELECTRODE MATERIALS WITH HIGH OPERATING VOLTAGE FOR LITHIUM BATTERIES - LICRYMN2-YO4 (0-LESS-THAN-OR-EQUAL-TO-Y-LESS-THAN-OR-EQUAL-TO-1)[J].Solid state ionics,1995(3/4):167-170.
[13]	Sigala C;Legal A;La Salle;Piffard Y et al.[J].Journal of the Electrochemical Society,2001,148(08):A812.
[14]	Ipandya K O;Grady W E;Hoffman R W .[J].Journal of Physical Chemistry,1990,94:21.
[15]	Okada M;Lee Yun sung;Masaki Yoshio.[J].Journal of Power Sources,2000(90):196.
[16]	Zh Qiming;Arman B;Zh Mijie et al.[J].Journal of the Electrochemical Society,1997,144(01):205.
[17]	Young Joo Lee;Charlotte Eng;Clare P Grey .[J].Journal of the Electrochemical Society,2001,148(03):A249.
[18]	Robertson AD.;Howard WF.;Lu SH. .M3+-MODIFIED LIMN2O4 SPINEL INTERCALATION CATHODES .2. ELECTROCHEMICAL STABILIZATION BY CR3+[J].Journal of the Electrochemical Society,1997(10):3505-3512.
[19]	Shen C H;Liu R S;Gundakaram R .[J].Journal of Power Sources,2001,102:21.
[20]	Yang Wensheng;Han Jingli;Yang Leiling.Meeting Abst facts of the Electrochemical Soc[C].Hawaii,USA,1999:290.
[21]	W Baochen;Xia Yongyao;Li Feng.[J].Journal of Power Sources,1993:539.
[22]	Akiva H;Kazunari Yoshizawa;Tokio Yamabe .[J].Journal of the Electrochemical Society,2000,147(01):4052.
[23]	Shigemura H;Sakaabe H;Kageyama H et al.[J].Journal of the Electrochemical Society,2001,148(07):A730.
[24]	Seung Tack Myung;Komaba S;Kumagai N .[J].Journal of the Electrochemical Society,2001,148(05):A482.
[25]	Bellitto C.;Branford WR.;Green MA.;Neumann DA.;DiMarco MG. .Cation distribution in Ga-doped Li1.02Mn2O4[J].Solid state ionics,2001(1/2):77-81.
[26]	HayashiN;Ikuta H;Wahara M .[J].Journal of the Electrochemical Society,1999,146(04):1351.
[27]	Yair Ein Eli;Howard W F;Sharon H Lu et al.[J].Journal of the Electrochemical Society,1998,145(04):1238.
[28]	Lourdes H;Julian Morales;Lius Sanchez et al.[J].Solid State Ionics,1999,118:179.
[29]	Robertson AD.;Averill WF.;Howard WF.;Lu SH. .M3+-MODIFIED LIMN2O4 SPINEL INTERCALATION CATHODES .1. ADMETAL EFFECTS ON MORPHOLOGY AND ELECTROCHEMICAL PERFORMANCE[J].Journal of the Electrochemical Society,1997(10):3500-3505.
[30]	Yang K Sun;Yan Seok Joen .[J].Electrochemistry Communications,1999,1:597.
[31]	Yair Ein-Eli;John T. Vaughey;Michael M. Thackeray;Sanjeev Mukerjee;Xiao Q. Yang;James McBreen .LiNi{sub}xCu{sub}(0.5-x)Mn{sub}1.5O{sub}4 spinel electrodes, superior high-potential cathode materials for Li Batteries I. electrochemical and structural studies[J].Journal of the Electrochemical Society,1999(3):908-913.
[32]	Amatucci G G;Perera N;Zheng T et al.[J].Journal of the Electrochemical Society,2001,148(02):A171.
[33]	Yang-Kook Sun;Bookeun Oh;Hwack Joo Lee .Synthesis and electrochemical characterization of oxysulfide spinel LiAl{sub}0.15Mn{sub}1.85O{sub}3.97S{sub}0.03 cathode materials for rechargeable batteries[J].Electrochimica Acta,2000(4):541-546.
[34]	Sang Ho Park;Kisoo Park;Yang Kook Sun et al.[J].Journal of the Electrochemical Society,2000,147(06):2116.
[35]	yang-Kook Sun;In-Hwan Oh .Cycling behavior of oxysulfide spinel LiCr_0.19Mn_1.81O_3.98S_0.02 cathode material which shows no capacity loss in the 3-V region[J].Journal of Power Sources,2001(1):132-136.
[36]	Yang-Kook Sun .Structural degradation mechanism of oxysulfide spinel LiAl_(0.24)Mn_(1.76)O_(3.98)S_(0.02) cathode materials on high temperature cycling[J].Electrochemistry communications,2001(4):199-202.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

尖晶石LiMn2O4的掺杂研究进展

Progress in Research on Doped Spinel LiMn2O4

参考文献