以氟化铵(NH4F)、乙二醇溶液为电解液,在不同的电解液温度(0～50℃)条件下,采用电化学阳极氧化法制备二氧化钛(TiO2)纳米管阵列.采用扫描电子显微镜(SEM)、X射线衍射仪(XRD)、紫外-可见分光光度计(UV-Vis)对TiO2纳米管阵列的形貌、结构和光学性能进行表征.结果表明,电解液温度高于20℃均能制备出纳米管阵列.光照下电解液温度40℃时制备的TiO2纳米管阵列具有最高光电流密度(Iph)0.2408 mA/cm2.以活性艳红X-3B为目标降解物,在室温、紫外光照射条件下考察了电解液温度对光催化活性的影响,结果显示电解液温度40℃时制备的TiO2纳米管阵列具有最高的光催化活性.
参考文献
| [1] | 李海雷,曹立新,柳伟,苏革.Ce/TiO2纳米管阵列的制备及光催化性能的研究[J].人工晶体学报,2012(04):926-930. |
| [2] | 杜锦阁,汪应灵,袁建梅.Ni2+/TiO2纳米管的光催化活性[J].人工晶体学报,2012(05):1405-1409. |
| [3] | 耿翀,严清峰,王晓青,沈德忠.阳极氧化法制备TiO2有序多孔薄膜[J].人工晶体学报,2013(05):794-798. |
| [4] | Rui Liu;Wein-Duo Yang;Liang-Sheng Qiang;Jian-Fu Wu .Fabrication of TiO_2 nanotube arrays by electrochemical anodization in an NH4F/H3PO4 electrolyte[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2011(19):6459-6466. |
| [5] | 蔡芳共,杨峰,赵勇,程翠华.温度控制TiO2纳米管及管/线复合阵列的制备[J].无机化学学报,2011(03):504-508. |
| [6] | Bing-Xin Lei;Qiu-Ping Luo;Zhen-Fan Sun .Fabrication of partially crystalline TiO2 nanotube arrays using 1, 2-propanediol electrolytes and application in dye-sensitized solar cells[J].Advanced Powder Technology: The internation Journal of the Society of Powder Technology, Japan,2013(1):175-182. |
| [7] | Peng Song;Xiaoyan Zhang;Mingxuan Sun .Graphene oxide modified TiO2 nanotube arrays: enhanced visible light photoelectrochemical properties[J].Nanoscale,2012(5):1800-1804. |
| [8] | Lee Kheng Tan;Manippady K. Kumar;Wen Wen An .Transparent, Well-Aligned TiO2 Nanotube Arrays with Controllable Dimensions on Glass Substrates for Photocatalytic Applications[J].ACS applied materials & interfaces,2010(2):498-503. |
| [9] | Doohun Kim;Andrei Ghicov;Sergiu P. Albu;Patrik Schmuki .Bamboo-Type TiO2 Nanotubes: Improved Conversion Efficiency in Dye-Sensitized Solar Cells[J].Journal of the American Chemical Society,2008(49):16454-16455. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%