欢迎登录材料期刊网

材料期刊网

高级检索

通过自由基溶液聚合法,在氧化石墨烯(GO)水溶液中合成聚N,N-二甲基丙烯酰胺/氧化石墨烯(PDMA/GO)纳米复合第一网络水凝胶,之后以N,N-亚甲基双丙烯酰胺(BIS)为交联剂引入化学交联聚丙烯酸(PAA)作为第二网络制备高强度的GO纳米复合双网络水凝胶.通过热重分析、力学性能测试、pH敏感性研究了第二单体从和GO浓度对GO纳米复合双网络水凝胶性能的影响.结果发现,热稳定性、力学性能随GO含量的增加而增加,随AA含量的增加先增加后减小.当pH>4.25时,GO纳米复合双网络水凝胶具有pH敏感性.

参考文献

[1] 向康,刘春华,王平华,唐龙祥,王志刚.石墨烯纳米复合材料的制备及结构表征[J].高分子材料科学与工程,2011(10):42-45.
[2] Li, Z.;Shen, J.;Ma, H.;Lu, X.;Shi, M.;Li, N.;Ye, M. .Preparation and characterization of pH- and temperature-responsive nanocomposite double network hydrogels[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2013(4):1951-1957.
[3] 刘桂廷,杨云云,叶磊,闫付臻,徐伟,冉蓉.RAFT一步法制备温度和pH双重响应的多孔智能水凝胶及其性能[J].高分子材料科学与工程,2012(12):13-16.
[4] Bourlinos AB.;Gournis D.;Petridis D.;Szabo T.;Szeri A.;Dekany I. .Graphite oxide: Chemical reduction to graphite and surface modification with primary aliphatic amines and amino acids[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(15):6050-6055.
[5] 王亚茹,戴玉芳,龚静华,马敬红.PDMAA/Clay纳米复合水凝胶的制备与性能[J].东华大学学报(自然科学版),2011(06):671-676.
[6] Haraguchi K.;Takehisa T.;Fan S. .Effects of clay content on the properties of nanocomposite hydrogels composed of poly(N-isopropylacrylamide) and clay[J].Macromolecules,2002(27):10162-10171.
[7] Kan, L.;Xu, Z.;Gao, C. .General avenue to individually dispersed graphene oxide-based two-dimensional molecular brushes by free radical polymerization[J].Macromolecules,2011(3):444-452.
[8] Gong, J.P. .Why are double network hydrogels so tough?[J].Soft matter,2010(12):2583-2590.
[9] Naficy, S.;Razal, J.M.;Whitten, P.G.;Wallace, G.G.;Spinks, G.M. .A pH-sensitive, strong double-network hydrogel: Poly(ethylene glycol) methyl ether methacrylates-poly(acrylic acid)[J].Journal of Polymer Science, Part B. Polymer Physics,2012(6):423-430.
[10] Jinghong Ma;Yajing Xu;Qingsong Zhang .Preparation and characterization of pH-and temperature-responsive semi-IPN hydrogels of carboxymethyl chitosan with poly(N-isopropyl acrylamide)crosslinked by clay[J].Colloid and polymer science,2007(4):479-484.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%