采用常规铸造和喷射成形工艺分别制备了H13钢,应用OM、SEM、XRD等方法研究了铸态、喷射沉积态及过喷粉的组织.采用LMS-30粒度仪对过喷粉进行了粒度分析.结果表明:铸态H13钢为粗大的枝晶组织,合金元素与碳化物偏析严重,而喷射成形H13钢为细小的等轴晶组织,几乎没有碳化物,含有较多的残余奥氏体.过喷粉是枝晶组织,随粉末尺寸的减小,一次枝晶变小,二次枝晶臂已不明显,是欠发达枝晶组织.雾化压力的增加对小颗粒过喷粉的尺寸和数量影响甚微,但会明显减小大颗粒过喷粉末的尺寸,并增加其数量.喷射成形等轴晶的形成机制在气液比偏小时以未破碎枝晶的均质化与碎断枝晶的连接长大为主,而在气液比偏高时以大量破碎枝晶作为异质形核核心为主.
参考文献
[1] | ASM International Handbook Committee.Metals handbook[M].USA:ASM International,1990:93. |
[2] | 周健,马党参,刘宝石,康爱军,李向阳.H13钢带状偏析演化规律研究[J].钢铁研究学报,2012(04):47-52,57. |
[3] | 霍晓阳.影响H13热作模具钢等向性的因素[J].钢铁研究学报,2008(11):47-50,54. |
[4] | Cole G S .Inhomogeneities and their controlvia solidification[J].Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science,1971,2B(02):357. |
[5] | Grant P S .Spray forming[J].Progress in Materials Science,1995,39:497. |
[6] | Lachenicht V;Scharf G;Zebrowski D et al.Spray forming-A promising process for making high-quality steels and alloys[J].Metall (Berlin),2011,54(09):656. |
[7] | Brooks R G;Moore C;Leatham A G et al.Osprey process[J].Powder Metallurgy,1977,20(02):100. |
[8] | Leatham A G;Lawly A .The osprey process:Principles and applications[J].International Journal of Powder Metallurgy,1993,29(04):321. |
[9] | Lavernia E J;Wu Y.Spray atomization and deposition[M].New York:John Wiley and Sons,Inc,1996:5. |
[10] | Lin YJ;McHugh KM;Zhou YZ;Lavernia EJ .Microstructure and hardness of spray-formed chromium-containing steel tooling[J].Scripta materialia,2006(7):581-584. |
[11] | Willnecker R;Herlach D M;Feuerbacher B .Grain refinement induced by a critical crystal growth velocity in undercooled melts[J].Applied Physics Letters,1990,56(04):324. |
[12] | Herlach DM.;Karma A.;Schwarz J.;Eckler K. .Grain refinement through fragmentation of dendrites in undercooled melts[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2001(0):20-25. |
[13] | Rieker C;Morris D G .Equiaxed microstructure by rapid solidification[J].Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing,1991,133:854. |
[14] | Haifeng Wang;Feng Liu;Gencang Yang .Experimental study of grain refinement mechanism in undercooled Ni-15at. % Cu alloy[J].Journal of Materials Research,2010(10):1963-1974. |
[15] | Mullis AM.;Cochrane RF. .GRAIN REFINEMENT AND THE STABILITY OF DENDRITES GROWING INTO UNDERCOOLED PURE METALS AND ALLOYS[J].Journal of Applied Physics,1997(8):3783-3790. |
[16] | Liang X;Earthman J C;Lavernia E J .On the mechanism of grain formation during spray atomization and deposition[J].ACTA METALLURGICA ET MATERIALIA,1992,40(11):3003. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%