钒钛铁精矿是一种铁、钒、钛等多元素共生的复合矿,具有很高的综合利用价值.采用实验室转底炉对钒钛铁精矿内配碳球团进行了高温快速还原的可行性研究,通过正交试验考察了配碳比、还原温度、添加剂、还原时间等参数对球团金属化率的影响.结果表明:配碳比1.5 t 1、还原温度1 350℃、添加剂2%碳酸钠、还原时间20rain时金属化率可以达到88%以上.对原料、还原样品进行x射线衍射分析表明,钒钛铁精矿粉中的磁铁矿、钛磁铁矿和钛铁矿通过还原转变为单质铁、含铁黑钛石.
参考文献
[1] | 汪琦.铁矿含碳球团技术[M].北京:冶金工业出版社,2005 |
[2] | 高运明,余方超.含碳球团高温抗压强度的实验测定[J].武汉科技大学学报(自然科学版),2006(02):109-111. |
[3] | Kasai A;Matsu Yamam.Development of Carbon Composite Iron Ore Hot Briquette and Basic Investigation on Its Strength Enhancing Mechanism and Reducibility[A].Tokyo:MEXT,2003:205. |
[4] | Yoshiyuki MATSUI;Muneyoshi SAWAYAMA;Akito KASAI .Reduction Behavior of Carbon Composite Iron Ore Hot Briquette in Shaft Furnace and Scope on Blast Furnace Performance Reinforcement[J].ISIJ International,2003(12):1904-1912. |
[5] | Kasai A;Matsu Yamam .Reduction and Carburization of Ca on Composite Iron Ore Hot Briquette on Condition of Increasing in Temperature[J].Current Advancements in Molecular Medicines,2003,16(02):95. |
[6] | 邱冠周;姜涛;徐经沧.冷固结球团直接还原[M].长沙:中南大学出版社,2001 |
[7] | 吴仁林.冷固结球团的研究和应用[J].炼铁,1994(02):26. |
[8] | 高文星,董凌燕,陈登福,温良英.煤基直接还原及转底炉工艺的发展现状[J].矿冶,2008(02):68-73. |
[9] | 范晓慧,邱冠周,姜涛,朱德庆,黄柱成,徐经沧.我国直接还原铁生产的现状与发展前景[J].炼铁,2002(03):53-55. |
[10] | 黄雄源,周兴灵.现代非高炉炼铁技术的发展现状与前景(一)[J].金属材料与冶金工程,2007(06):49-56. |
[11] | Nasu T.;Tokumitsu K. .Reduction of Iron-Oxide by Ball-Milling with Hydrogen Gas Flow[J].Materials Science Forum,2000(Pt.1):435-440. |
[12] | Yoshimi Shinya T;Yoshiaki K;Lepinski J et al.Reduction of Hematite to Magnetite Induced by Hydrogen Ion Implantation[J].Journal of Physics D: Applied Physics,1996,29(01):8. |
[13] | Makhlij A A;Kovalenko A A;Tsvetkov Y V.Reduction of Surface Layers of Magnetite Single Crystals by Accelerated Hydrogen Ions[J].Fizikai Khimiya Obrabotki Materialov,1995(05):103. |
[14] | Bullard D E;Lynch D C .Reduction of Ilmenite in a Non-Equilibrium Hydrogenplasma[J].Metall Mater Trans B:Process Metallurgy and Materials Processing Science,1997,288(03):517. |
[15] | Sastri M V C;Viswanath R P;Viswanathan B .Studies on the Reduction of Iron Oxide With Hydrogen[J].Hydrogen Energy Progress,1982,7(12):951. |
[16] | Prabhakaran K.;Shafi KVPM.;Ulman A.;Ajayan PM.;Homma Y.;Ogino T. .Low-temperature, carbon-free reduction of iron oxide[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,2002(1/2):L250-L254. |
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