先用乳液插层法制共沉胶,再通过熔融混炼法制备有机化蒙脱土(OMMT)/天然胶乳复合材料.研究复合材料的结构、拉伸性能、硬度、热性能.结果表明:OMMT/天然胶乳形成了插层型纳米结构.与天然橡胶相比,OMMT/天然胶乳复合材料的拉伸强度、硬度增加.当OMMT含量为6%时,能获得拉伸强度、断裂伸长率较优的材料.该OMMT/天然胶复合材料的力学性能超过白碳黑对材料的增强效果.
参考文献
[1] | Yen T. Vu;James E. Mark;Ly H. Pham;Martin Engelhardt .Clay Nanolayer Reinforcement of cis-1,4-Polyisoprene and Epoxidized Natural Rubber[J].Journal of Applied Polymer Science,2001(6):1391-1403. |
[2] | Joly S.;Garnaud G.;Ollitrault R.;Bokobza L.;Mark JE. .Organically modified layered silicates as reinforcing fillers for natural rubber[J].Chemistry of Materials,2002(10):4202-4208. |
[3] | Kim JT.;Lee DY.;Oh TS.;Lee DH. .Characteristics of nitrile-butadiene rubber layered silicate nanocomposites with silane coupling agent[J].Journal of Applied Polymer Science,2003(10):2633-2640. |
[4] | Essawy H;El-Nashar D .The use of montmorillonite as a reinforcing and compatibilizing filler for NBR/SBR rubber blend[J].Polymer Testing,2004(7):803-807. |
[5] | Zhenjun Zhang;Lina Zhang;Yang Li;Hongde Xu .New fabricate of styrene-butadiene rubber/montmorillonite nanocomposites by anionic polymerization[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(1):129-136. |
[6] | Valadares LF;Leite CAP;Galembeck F .Preparation of natural rubber-montmorillonite nanocomposite in aqueous medium: evidence for polymer-platelet adhesion[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(2):672-678. |
[7] | Hrachova J;Komadel P;Chodak I .Effect of montmorillonite modification on mechanical properties of vulcanized natural rubber composites[J].Journal of Materials Science,2008(6):2012-2017. |
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