以聚乙二醇(PEG),碳酸氢铵分别为模板和沉淀剂,通过简单的水热改性制备了前驱体Ni(OH)2,然后经热处理得到NiO.用X射线衍射(XRD)和扫描电子显微镜(SEM)对产物的结构和形貌进行表征,用循环伏安(CV)和交流阻抗(AC)对产物的电化学性能进行测试.结果表明,所制备的氧化镍,在0.0-0.5V(vs.SCE)的电位范围内,具有良好的电容性能和循环稳定性,并且在6mol/L的氢氧化钾溶液中单电极的放电比电容在0.25V电位下为397F/g,当电位为0.35V时比电容达到了483F/g.
参考文献
[1] | 刘政,毛卫民.碳纳米管及其在汽车中的应用前景[J].金属功能材料,2005(04):39-43. |
[2] | Li X L et al.[J].Microporous and Mesoporous Materials,2010,131(1-3):303-309. |
[3] | Emmenegger C et al.[J].Journal of Power Sources,2003,124:321-329. |
[4] | Subramanian V et al.[J].Journal of Power Sources,2006,159(01):361-364. |
[5] | Li XL;Li WJ;Chen XY;Shi CW .Hydrothermal synthesis and characterization of orchid-like MnO2 nanostructures[J].Journal of Crystal Growth,2006(2):387-389. |
[6] | P. Staiti;F. Lufrano .Study And Optimisation Of Manganese Oxide-based Electrodes For Electrochemical Supercapacitors[J].Journal of Power Sources,2009(1):284-289. |
[7] | Wu M Q et al.[J].Journal of Porous Materials,2006,13:407-412. |
[8] | Li H L et al.[J].Materials Chemistry and Physics,2004,83:260-264. |
[9] | Xian-Ming Liu;Xiao-Gang Zhang;Shao-Yun Fu .Preparation of urchinlike NiO nanostructures and their electrochemical capacitive behaviors[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2006(3):620-627. |
[10] | Li XL;Chen XJ;Chen XY;Han CL;Shi CW .Hydrothermal synthesis and characterization of VO2 (B) nanorods array[J].Journal of Crystal Growth,2007(1):43-47. |
[11] | Kannan AM.;Manthiram A. .Synthesis and electrochemical evaluation of high capacity nanostructured VO2 cathodes[J].Solid state ionics,2003(3/4):265-271. |
[12] | 邢伟,李丽,阎子峰,LU Gao-Qing.介孔氧化镍的合成、表征和在电化学电容器中的应用[J].化学学报,2005(19):1775-1781. |
[13] | Wu M S;Hsieh H H .[J].Electrochimica Acta,2008,53:3427-3435. |
[14] | 王兴磊,何宽新,张校刚,米红宇,罗建民.溶剂热法合成蜂巢状氧化镍及其电化学电容性能[J].无机化学学报,2007(09):1533-1537. |
[15] | Li X L et al.[J].Transactions of Nonferrous Metals Society of China,2009,19(03):620-625. |
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