欢迎登录材料期刊网

材料期刊网

高级检索

采用丙烯酸羟乙酯(HEA)与马来酸酐(MA)的开环反应得到半酯AEOEA,再通过半酯AEOEA与甲基丙烯酸缩水甘油酯(GMA)的开环反应得到一种三官能团直链高活性单体AEHMPM.通过实时红外(RT-IR)检测了引发剂种类、引发剂浓度以及不同光强对AEHMPM光聚合的影响;用动态力学分析仪(DMA)检测了AEHMPM固化后材料的储能模量E'和玻璃化转变温度(Tg).测试结果表明:AEHMPM的聚合速率、双键转化率及其固化后的交联密度均优于商业化的三羟甲基丙烷三丙烯酸酯(TMPTA).

参考文献

[1] Xu, F.;Yang, J.-L.;Gong, Y.-S.;Ma, G.-P.;Nie, J..A fluorinated photoinitiator for surface oxygen inhibition resistance[J].Macromolecules,20123(3):1158-1164.
[2] Ibrahim, A.;Stefano, L.D.;Tarzi, O.;Tar, H.;Ley, C.;Allonas, X..High-performance photoinitiating systems for free radical photopolymerization. Application to holographic recording[J].Photochemistry and Photobiology: An International Journal,20136(6):1283-1290.
[3] Kricheldorf, HR;Yashiro, T;Weidner, S.Isomerization-Free Polycondensations of Maleic Anhydride with alpha,omega-Alkanediols[J].Macromolecules,200917(17):6433-6439.
[4] Boutevin G.;Robin JJ.;Boutevin B.;Ameduri B..Synthesis and thermal properties of bismaleate and bisfumarate telechelic oligomers from hydroxytelechelic polybutadienes[J].Journal of Applied Polymer Science,20031(1):72-79.
[5] 解一军;刘盘阁;姬荣琴;李佐邦.半酯法合成环氧丙烯酸酯型光敏涂料[J].河北工业大学学报,2002(2):67-73.
[6] 赵子千;姚伯龙;陈明清.MAn-HTPB改性环氧丙烯酸酯光敏涂料的研制[J].上海涂料,2007(3):34-37.
[7] Dong Jiang;Yuan Yuan Wang;Yan Nan Xu;Li Yi Dais.Ring-opening of cyclic anhydrides using ionic liquids[J].Journal of chemical research: reviews and research papers from all branches of chemistry,20093(3):167-169.
[8] D.N.Aver'yanov;A.V.Batrakova;Ya.D.Samuilov.Esterification of Dicarboxylic Acids with Benzyl Alcohol under the Action of the Microwave Radiation[J].Russian Journal of General Chemistry,200810(10):1920-1923.
[9] Nayak BR;Mathias LJ.A novel photoinimer for the polymerization of acrylates and methacrylates[J].Journal of Polymer Science, Part A. Polymer Chemistry,200522(22):5661-5670.
[10] Jansen JFGA.;Dias AA.;Dorschu M.;Coussens B..Fast monomers: Factors affecting the inherent reactivity of acrylate monomers in photoinitiated acrylate polymerization [Review][J].Macromolecules,200311(11):3861-3873.
[11] Lon J.Mathias;Bianca S.Shemper;Matthieu Alirol;Jean-Francois Morizur.Synthesis of New Hydroxylated Monomers Based on Methacrylate, Dimethacrylate, and Tetramethacrylate Michael Adducts and Photopolymerization Kinetics of Bulk Cross-Linkers[J].Macromolecules,20049(9):3231-3238.
[12] Hill LW..CALCULATION OF CROSSLINK DENSITY IN SHORT CHAIN NETWORKS [Review][J].Progress in Organic Coatings: An International Review Journal,19973(3):235-243.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%