采用双辉等离子表面合金化技术对TiNi合金进行表面渗钼合金化处理；采用光学显微镜、辉光放电光谱仪和扫描电镜对合金化试样的截面及表面进行了表征,采用显微硬度计、硬度计、往复磨损试验机及白光干涉仪对合金化试样的表面硬度、结合强度及摩擦学性能进行了测试.结果表明:TiNi合金表面渗钼合金化后形成了三层结构的合金层,从外向内依次是钼沉积层、富钛合金层和贫钼合金层；合金层与基体间形成了冶金结合,其表面硬度、耐磨性能与基体合金相比提高了2.5倍和2个数量级.
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