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为了研究AZ31镁合金微弧氧化(MAO)涂层腐蚀速率的数学模型,选取不同的过程参数(包括脉冲频率、电压、氧化时间和电解液浓度),采用微弧氧化技术和磷酸三钠电解液体系,在镁合金基体上制备了耐蚀涂层。研究了不同脉冲频率下制备的MAO涂层在仿生体液中浸泡1、5和7 d后的极化曲线,测试了不同条件下制备的镁合金 MAO 涂层在浸泡不同时间后的腐蚀电流密度,对不同微弧氧化过程参数及浸泡时间进行了主成分分析,建立了腐蚀速率的数学模型。结果表明,MAO涂层的腐蚀电流密度小于镁合金基体,脉冲频率对腐蚀速率起主导作用。将不同过程参数下制备的镁合金 MAO 涂层在仿生体液中浸泡24 h,利用Tafel曲线拟合得到的腐蚀电流密度与由回归方程计算所得的模拟电流密度相比,相对误差小于5%,而且其多元评定系数为0.9021,表明所建立的回归方程能可靠地用来模拟不同参数下制备的镁合金 MAO 涂层在浸泡不同时间下的腐蚀电流密度,为预测和控制镁及镁合金 MAO 涂层的腐蚀速率提供指导。

The mathematical model for corrosion rate of a micro-arc oxidation (MAO) coating on AZ31 magnesium was studied. The corrosion resistant coating on AZ31 Mg alloys was prepared from a Na3PO4 bath by MAO technology using various parameters including pulse frequency, voltage, oxidation time, and electrolyte concentration. The polarization curves for MAO coatings prepared at different pulse frequencies after immersion in simulated body fluid (SBF) for 1, 5, and 7 days were examined. The corrosion current densities of the MAO coatings prepared under different conditions after immersing for different time were measured. The principal component analysis for various parameters of MAO process and immersion time in SBF was carried out. A mathematical model for corrosion rate was established. The results showed that the corrosion current density of MAO coating is smaller than that of untreated Mg alloy substrate. Pulse frequency plays a leading role for corrosion rate. The relative error of the corrosion current density fitted by Tafel curves for the MAO coatings prepared under different process parameters after immersion in SBF for 24 h is less than 5%, as compared with the corrosion current densities calculated by using the regression equation. The coefficient of multiple determination is 0.902 1, implying that the regression equation can be reliably used for predicting the corrosion current densities of MAO coatings prepared on magnesium alloy under various parameters and immersed in SBF for different time. The method can be used for predicting and controlling the corrosion rates of MAO coatings on Mg and Mg alloys.

参考文献

[1] Witte F .The history of biodegradable magnesium implants: a review.[J].Acta biomaterialia,2010(5):1680-1692.
[2] Hornberger,H.;Virtanen,S.;Boccaccini,A.R. .Biomedical coatings on magnesium alloys - A review[J].Acta biomaterialia,2012(7):2442-2455.
[3] MUELLER W D;DE MELE M F L;NASCIMENTO M L et al.Degradation of magnesium and its alloys:Dependence on the composition of the synthetic biological media[J].Journal of Biomedical Materials Research Part A,2009,90(02):487-495.
[4] Witte F;Kaese V;Haferkamp H;Switzer E;Meyer Lindenberg A;Wirth CJ;Windhagen H .In vivo corrosion of four magnesium alloys and the associated bone response.[J].Biomaterials,2005(17):3557-3563.
[5] Wenjin Zhang;Meiheng Li;Qian Chen;Wangyu Hu;Wenmei Zhang;Wang Xin .Effects of Sr and Sn on microstructure and corrosion resistance of Mg-Zr-Ca magnesium alloy for biomedical applications[J].Materials & design,2012(Aug.):379-383.
[6] HARANDI S E;IDRIS M H;JAFARI H .Effect of forging process on microstructure,mechanical and corrosion properties of biodegradable Mg-1Ca alloy[J].Materials&Design,2011,32(05):2596-2603.
[7] 李智.镁基材料表面微弧氧化生物医用陶瓷涂层研究进展[J].电镀与涂饰,2011(06):29-33.
[8] 钟涛生,蒋百灵,李均明.微弧氧化技术的特点、应用前景及其研究方向[J].电镀与涂饰,2005(06):47-50.
[9] 陈显明,罗承萍,刘江文.镁合金微弧氧化膜层结构分析[J].中国表面工程,2009(05):45-49.
[10] 李勇,牛丽媛,高光亮,林继兴,刘兰云.微弧氧化工艺及封孔处理对镁合金耐蚀性能的影响[J].表面技术,2008(06):14-17.
[11] 尚伟,温玉清,李秀广,黄明仁,卢钇成.AZ91D镁合金微弧氧化电参数对其耐蚀性的影响[J].表面技术,2012(01):37-40.
[12] 常林荣,曹发和,蔡景顺,刘文娟,张昭,张鉴清.交变方波电源参数对镁合金AZ91D微弧氧化的影响[J].中国有色金属学报(英文版),2011(02):307-316.
[13] 王淑艳,夏永平,陆正萍,彭赞瑜,胡芮.电解液组分对AZ91D镁合金微弧氧化膜层耐蚀性的影响[J].中国表面工程,2011(05):38-44.
[14] 梁军,田军,周金芳,刘维民,徐洮.磷酸盐-氢氧化钾溶液中镁合金微弧氧化膜层结构和性能研究[J].电镀与涂饰,2005(12):4-7.
[15] 马颖,詹华,马跃洲,吕维玲,冯君艳,高唯.电参数对AZ91D镁合金微弧氧化膜层微观结构及耐蚀性的影响[J].中国有色金属学报,2010(08):1467-1473.
[16] 梁军,郝京诚.电流密度对镁合金微弧氧化膜结构和性能的影响[J].材料保护,2007(08):24-26,29.
[17] 梁永政,师会超.微弧氧化时间对AZ61镁合金陶瓷膜形貌及性能的影响[J].材料保护,2010(10):39-41.
[18] 吕维玲,马颖,陈体军,徐卫军,杨健,郝远.氧化时间对AZ91D镁合金微弧氧化膜微观组织和性能的影响[J].中国有色金属学报,2009(08):1385-1391.
[19] 郭洪飞,安茂忠,徐莘,霍慧彬.镁合金微弧氧化配方的优化及膜层耐蚀性能评价[J].电镀与涂饰,2004(06):1-4,11.
[20] 章志友,赵晴,刘月娥.镁合金微弧氧化工艺及陶瓷层耐蚀性能研究[J].电镀与涂饰,2008(05):30-33,48.
[21] KOKUBO T;KUSHITANI H;SAKKA S et al.Solutions able to reproduce in vivo surface-structure changes in bioactive glass-ceramic A-W[J].Journal of Biomedical Materials Research,1990,24(06):721-734.
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