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采用液相及动态熔融法使沥青炭均匀包覆于天然石墨的表面,观察天然石墨的表面结构,测量其物理参数,考核复合材料的充放电性能.结果表明:天然石墨表面存在沥青热解碳,粒径、振实密度增大,复合炭材料的充放电容量、循环性能都得到提高.添加5%沥青经400℃炭化3h、850℃热处理2h的样品,电化学性能最好,可逆容量为362mAh/g,不可逆容量为31.7mAh/g,首次充放电效率为92.0%,30个循环周期后,容量保持率为96.6%

参考文献

[1] GUO Hua-jun,LI Xin-hai,WANG Zhi-xing,PENG Wen-jie,GUO Yong-xing.Mild oxidation treatment of graphite anode for Li-ion batteries[J].中南工业大学学报(英文版),2005(01):50-54.
[2] Hongyu W;Masaki Y;Takeshi A et al.[J].Journal of the Electrochemical Society,2002,149(04):499-503.
[3] Guo Huajun,li Xinhai,WANG Zhixing,Peng Wenjie,Guo Yongxing.Effect of lithium or aluminum substitution on the characteristics of graphite for anode of lithium ion batteries[J].稀有金属(英文版),2003(04):280-284.
[4] Beguin, F;Chevallier, F;Vix, C;Saadallah, S;Rouzaud, JN;Frackowiak, E .A better understanding of the irreversible lithium insertion mechanisms in disordered carbons[J].The journal of physics and chemistry of solids,2004(2/3):211-217.
[5] Masaki Yoshio;Hongyu Wang;Kenji Fukuda;Yoichiro Hara;Yoshio Adachi .Effect of carbon coating on electrochemical performance of treated natural graphite as lithium-ion battery anode material[J].Journal of the Electrochemical Society,2000(4):1245-1250.
[6] 陈猛,肖斌,杨闯,李金媛.羧甲基纤维素包覆天然石墨性能的研究[J].化学工程师,2006(03):61-63.
[7] Ding YS;Li WN;Iaconetti S;Shen XF;DiCarlo J;Galasso FS;Suib SL .Characteristics of graphite anode modified by CVD carbon coating[J].Surface & Coatings Technology,2006(9):3041-3048.
[8] Wang Guoping;Zhang Bolan;Yue Min et al.[J].Solid State Ionics,2005,176:905-909.
[9] Sato Y;Tanuma K;Takayama T et al.[J].Journal of Power Sources,2001,97-98:165-170.
[10] 余晴春,熊勇,吴益华.热解沥青碳材料锂的嵌入研究[J].电源技术,1999(04):218.
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