材料导报, 2010, 24(22): 13-15.
镁合金表面AlCl3-NaCl熔盐置换扩渗铝涂层的热力学研究
何美凤 1, , 刘磊 2, , 仵亚婷 {"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"热力学计算表明,用氩氯混合气体吹入钢液,当VAr/VCl2=9时,氯可将钢中氢的质量分数由6×10-6降至(1～2)×10-6;耗氯量为0.14 m3/t,其中40%用于脱氢.本文为原苏联发明专利No1084346[5]的原理之二.","authors":[{"authorName":"徐世铮","id":"c7248f43-42f9-4ce3-be44-c37837ad653a","originalAuthorName":"徐世铮"},{"authorName":"B.G.斯克里亚宾","id":"9ccc2d5e-c258-4eca-8cf8-80dca5ec17d1","originalAuthorName":"B.G.斯克里亚宾"},{"authorName":"A.Г.巴诺马连柯","id":"1d91fbb8-7756-47f3-850f-14c2511c580a","originalAuthorName":"A.Г.巴诺马连柯"}],"doi":"10.3969/j.issn.1671-6620.2006.03.005","fpage":"177","id":"7db72bc7-4940-45dc-b019-273966a104aa","issue":"3","journal":{"abbrevTitle":"CLYYJXB","coverImgSrc":"journal/img/cover/CLYYJXB.jpg","id":"17","issnPpub":"1671-6620","publisherId":"CLYYJXB","title":"材料与冶金学报"},"keywords":[{"id":"11bfa3a6-ac39-48db-af22-5fb04748c2bc","keyword":"氩氯混合气体","originalKeyword":"氩氯混合气体"},{"id":"48cd991f-ec49-4683-8896-07252ae7f793","keyword":"氯选择脱氢-(Ar/Cl2)","originalKeyword":"氯选择脱氢-(Ar/Cl2)"}],"language":"zh","publisherId":"clyyjxb200603005","title":"吹入氩氯混合气体钢液脱氢工艺参数(Ar/Cl2)的确定","volume":"5","year":"2006"},{"abstractinfo":"采用Cl2/Ar感应耦合等离子体对InP进行了刻蚀.讨论了直流自偏压、ICP功率、气体总流量和气体组分等因素对刻蚀速率和粗糙度的影响.结果表明Cl2/Ar气体组分是决定刻蚀效果的重要因素.当Cl2含量为30%左右时,刻蚀中的物理溅射与化学反应过程趋于平衡,刻蚀速率处于峰值区,同时刻蚀粗糙度也可达到最小值.SEM照片显示刻蚀表面光洁,侧壁陡直.","authors":[{"authorName":"朱海波","id":"137aa945-522c-41c5-9f20-1e887622c498","originalAuthorName":"朱海波"},{"authorName":"李晓良","id":"cddd2b94-75b6-455a-8d51-637bba064cb8","originalAuthorName":"李晓良"}],"doi":"10.3969/j.issn.1007-4252.2005.03.025","fpage":"377","id":"bf672fe5-f2a2-4c6e-9862-42b3e1dc309b","issue":"3","journal":{"abbrevTitle":"GNCLYQJXB","coverImgSrc":"journal/img/cover/GNCLYQJXB.jpg","id":"34","issnPpub":"1007-4252","publisherId":"GNCLYQJXB","title":"功能材料与器件学报 "},"keywords":[{"id":"affef9c0-7c9d-4781-bad7-d28d5c2ccbb7","keyword":"干法刻蚀","originalKeyword":"干法刻蚀"},{"id":"f41cc89c-3451-42a5-98e6-2950d270b3ff","keyword":"感应耦合等离子体","originalKeyword":"感应耦合等离子体"},{"id":"d7f5c3d2-b657-4624-9e69-1bc40900d610","keyword":"InP","originalKeyword":"InP"},{"id":"fa5d19de-a153-4c8f-b5a3-d69f57175d52","keyword":"刻蚀速率","originalKeyword":"刻蚀速率"},{"id":"69a87952-5fc7-4487-ac40-bcecc0d1d516","keyword":"粗糙度","originalKeyword":"粗糙度"}],"language":"zh","publisherId":"gnclyqjxb200503025","title":"Cl2/Ar感应耦合等离子体刻蚀InP工艺研究","volume":"11","year":"2005"},{"abstractinfo":"本文对微波解离Cl2产生Cl,与HN3/He的混合气体反应产生的激发态粒子NCl(a1△)和NCl(b1∑)进行了实验研究.对NCl(a1△)和NCl(b1∑)的荧光光谱进行了测量并对光谱强度沿气流方向的变化趋势以及依赖几种不同气体流量和配比的变化关系进行了研究.给出了NCl(a1△)和NCl(b1∑)产生的最佳实验参数及配比关系,并对结果做了讨论.","authors":[{"authorName":"多丽萍","id":"5f6e1f5f-c178-4fbc-b67b-86f8bfcdb12d","originalAuthorName":"多丽萍"},{"authorName":"唐书凯","id":"671ef530-25ca-4a67-aeae-5f2e1f572d3f","originalAuthorName":"唐书凯"},{"authorName":"于海军","id":"a869d71f-32f2-4614-b6b6-b06ebfbeccfb","originalAuthorName":"于海军"},{"authorName":"闵祥德","id":"29be372e-5867-4f93-99c7-a2d71996615a","originalAuthorName":"闵祥德"},{"authorName":"桑凤亭","id":"d461e484-edef-4146-b7d2-6d338953b1cb","originalAuthorName":"桑凤亭"},{"authorName":"杨柏龄","id":"9b855075-9c6a-4088-b06f-fcdfc97af1e6","originalAuthorName":"杨柏龄"}],"doi":"10.3969/j.issn.1007-5461.2003.04.009","fpage":"426","id":"f3e4f0b2-d24e-4d9b-8fc0-071971011956","issue":"4","journal":{"abbrevTitle":"LZDZXB","coverImgSrc":"journal/img/cover/LZDZXB.jpg","id":"53","issnPpub":"1007-5461","publisherId":"LZDZXB","title":"量子电子学报 "},"keywords":[{"id":"f974078e-0bb9-4434-82b3-06d0d4e4d390","keyword":"NCl(a1△)和NCl(b1∑)","originalKeyword":"NCl(a1△)和NCl(b1∑)"},{"id":"20a3f897-b77c-4255-829d-dcfca3e5f6ce","keyword":"C1/Cl2/He+HN3/He","originalKeyword":"C1/Cl2/He+HN3/He"},{"id":"70fd1fb8-cf26-4c86-b298-342651bca9f2","keyword":"激发态粒子","originalKeyword":"激发态粒子"}],"language":"zh","publisherId":"lzdzxb200304009","title":"Cl/Cl2/He+HN3/He反应体系的实验研究","volume":"20","year":"2003"},{"abstractinfo":"以CuCl2和邻菲啰啉(phen)为原料,在甲醇和乙醇混合溶剂中制备了Cu(phen)Cl2,采用傅里叶红外光谱、热重分析和H2程序升温还原对其进行了表征,并研究了其在甲醇氧化羰基化合成碳酸二甲酯(DMC)反应中的催化性能.结果表明,Cu(phen)Cl2不仅具有较高的热稳定性,而且因phen与Cu(Ⅱ)间的σ-π配位作用而具有较高的催化活性.在催化剂浓度0.011mol/L,反应温度150℃,反应压力4.0 MPa和p(CO)/p(O2)=19的条件下,生成DMC的转化数(TON)可达51.5.研究还发现,反应存在诱导期,且TON随温度呈“M”形变化,据此提出了新的羰氧化反应机理.","authors":[{"authorName":"杜治平","id":"b92e9101-a5ea-4d3f-925a-7636880382fb","originalAuthorName":"杜治平"},{"authorName":"周彬","id":"e21e3d96-f2aa-4307-a019-a884405935a8","originalAuthorName":"周彬"},{"authorName":"黄丽明","id":"9451dae0-03d5-4a3a-a974-36a6c7d58bad","originalAuthorName":"黄丽明"},{"authorName":"黄晨","id":"8b28007b-284e-494b-98d5-b409ed317e0d","originalAuthorName":"黄晨"},{"authorName":"吴元欣","id":"e520c68a-e436-4e47-bb40-c4ed5f1aeecb","originalAuthorName":"吴元欣"},{"authorName":"王存文","id":"ce9877b0-38ec-4b76-bedb-eec02f04ff0b","originalAuthorName":"王存文"},{"authorName":"孙炜","id":"d965b523-e5f7-41ed-b46d-77c852ee7e2f","originalAuthorName":"孙炜"}],"doi":"10.3724/SP.J.1088.2012.11121","fpage":"736","id":"c822ae9e-de82-4cf9-8105-2b579c1f69dc","issue":"4","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"5550106f-8d27-4e9e-a6f1-ece98c23d860","keyword":"碳酸二甲酯","originalKeyword":"碳酸二甲酯"},{"id":"4d6e5aa9-b05a-429d-b4cc-1eda5de76222","keyword":"甲醇","originalKeyword":"甲醇"},{"id":"48c79dfd-6d41-41c9-875d-a58d6c4f9772","keyword":"氧化羰基化","originalKeyword":"氧化羰基化"},{"id":"a87aab29-eeb0-47a3-9b58-b2aaf782bcf5","keyword":"氯化铜","originalKeyword":"氯化铜"},{"id":"459474c5-f1b8-4f0b-ade3-c84f50756717","keyword":"邻菲哕啉","originalKeyword":"邻菲哕啉"},{"id":"c6ba5df3-c63c-422c-9cff-8a96a3101b9e","keyword":"配合物","originalKeyword":"配合物"}],"language":"zh","publisherId":"cuihuaxb201204023","title":"Cu(phen)Cl2催化甲醇氧化羰基化合成碳酸二甲酯","volume":"33","year":"2012"},{"abstractinfo":"制备了新型Pd(P-Phos)Cl2配合物,并通过1H,13C和31p核磁共振及X射线单晶衍射对其结构进行了确认及表征.结果表明,该配合物是室温有氧条件下Suzuki-Miyaura交叉偶联反应的高稳定高效催化剂,并具有广泛的底物适用性.催化剂用量较低,且转化数(TON)最高可达49000.","authors":[{"authorName":"葛轶岑","id":"e03affa1-0a3b-4b8e-8079-f80a3f8a6c2f","originalAuthorName":"葛轶岑"},{"authorName":"程雨晶","id":"b30cbdfd-a449-4cdc-ab6b-33168712f47e","originalAuthorName":"程雨晶"},{"authorName":"付海燕","id":"fc14c6f6-8e91-4117-a37b-217b4c3e1d68","originalAuthorName":"付海燕"},{"authorName":"郑学丽","id":"69770a3c-5583-4b42-ba97-b4dbdec8fe48","originalAuthorName":"郑学丽"},{"authorName":"李瑞祥","id":"e5dc2f8c-c012-40b8-9356-ac1db81825f1","originalAuthorName":"李瑞祥"},{"authorName":"陈华","id":"1210727e-f1c1-4618-b6e7-1a74ec1e18b5","originalAuthorName":"陈华"},{"authorName":"李贤均","id":"da8d6dd5-7a2f-4ab0-8e30-0fc4b67971dd","originalAuthorName":"李贤均"}],"doi":"10.1016/S1872-2067(12)60620-2","fpage":"1667","id":"c9c3b03c-5cac-470c-acf7-12a1039c5328","issue":"9","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"ab06fdce-23a3-4df8-a5d3-879f1005c794","keyword":"钯配合物","originalKeyword":"钯配合物"},{"id":"6e7ddb61-b936-4e32-9175-400e466d6cf8","keyword":"联吡啶双膦配体P-Phos","originalKeyword":"联吡啶双膦配体P-Phos"},{"id":"f83d1983-ebaa-4f23-a925-c4a46b997e0f","keyword":"Suzuki-Miyaura交叉偶联反应","originalKeyword":"Suzuki-Miyaura交叉偶联反应"},{"id":"3d106788-d6ff-4b6c-88a0-3d375ce36b9b","keyword":"室温","originalKeyword":"室温"},{"id":"8c40426c-7250-40c7-99ac-63bc833614ea","keyword":"空气","originalKeyword":"空气"}],"language":"zh","publisherId":"cuihuaxb201309005","title":"室温有氧条件下高稳定性Pd(P-Phos)Cl2配合物催化Suzuki-Miyaura交叉偶联反应","volume":"34","year":"2013"},{"abstractinfo":"为寻求高效低毒的新型顺铂类抗肿瘤药物,用K2PtCl4、乙二胺(en)、氟尿嘧啶(5-Fu)为原料,设计合成了顺铂类似物[pt(en)(5-Fu)2]C12配合物,由元素分析、红外光谱和质谱分析初步证实了其化学结构,用改良MTT、SRB法,选用K562、A549、Bel-7402、BIU-87、Bcap-37细胞株对其进行体外抗肿瘤活性测定.结果表明,所合成的配合物除在浓度为0.01、0.1 μg/mL时对K562细胞株抗肿瘤活性大于顺铂和氟尿嘧啶外,其它情况下的抗肿瘤活性均小于顺铂和氟尿嘧啶.该配合物仍有进一步研究的价值.","authors":[{"authorName":"钟文远","id":"1254d54a-ea26-4f98-82c0-ab2495ffa6a0","originalAuthorName":"钟文远"},{"authorName":"崔永春","id":"f76f8938-ecb1-4e58-a2fe-c6c5acf9bc15","originalAuthorName":"崔永春"},{"authorName":"范春兰","id":"c341add8-ff4e-4454-96d2-f0828b4e49e0","originalAuthorName":"范春兰"},{"authorName":"胡智兴","id":"c52ba8c3-ac5f-4508-9196-00da15b28d13","originalAuthorName":"胡智兴"},{"authorName":"李玛琳","id":"79a3cf27-eb7d-4d60-816b-17aeeb3036cc","originalAuthorName":"李玛琳"}],"doi":"10.3969/j.issn.1004-0676.2004.02.005","fpage":"20","id":"d6fc60f6-9769-4f2d-bd9d-e1aa43ff7dd8","issue":"2","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"758fc967-fa6b-41ff-a65b-b71c80c73286","keyword":"药学","originalKeyword":"药学"},{"id":"bfd02229-872d-4c30-a240-5290210eadee","keyword":"铂(Ⅱ)配合物","originalKeyword":"铂(Ⅱ)配合物"},{"id":"5073a4ec-7fd5-40b7-be6c-056c7017aa81","keyword":"合成","originalKeyword":"合成"},{"id":"bb69d24d-3d82-4d3d-b792-5a59ed01d97e","keyword":"抗肿瘤活性","originalKeyword":"抗肿瘤活性"}],"language":"zh","publisherId":"gjs200402005","title":"[Pt(en)(5-Fu)2]Cl2配合物的合成及抗肿瘤活性","volume":"25","year":"2004"},{"abstractinfo":"以金属锑为阳极,钛、不锈钢等导电材料为阴极,HCl溶液或含NaCl的HCl溶液为电解液,在单室电解槽中采用电化学牺牲阳极法溶解金属锑,制备了粒径为10 nm的超细金属锑,该金属锑与盐酸溶液反应生成了氯化锑溶液,再经水解得到了氯氧化锑Sb4O5Cl2.产品通过X射线粉末衍射(XRD)、扫描电子显微镜(SEM)和透射电镜(TEM)测试技术进行了表征.","authors":[{"authorName":"郑波","id":"4c0c0dbc-f118-4ed3-b09c-7bf9d0275d95","originalAuthorName":"郑波"},{"authorName":"马美华","id":"157b71e0-3178-4470-b7e0-59a4f6f98044","originalAuthorName":"马美华"},{"authorName":"顾建胜","id":"8fb3e3b6-91a2-4ae8-af31-0154ab0480d5","originalAuthorName":"顾建胜"}],"doi":"10.3969/j.issn.1000-0518.2007.02.024","fpage":"226","id":"3359df4d-fce1-4753-a7e5-8a0cb97a0396","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"9935ceaf-c139-4ead-a18d-02619c75a3e5","keyword":"氯氧化锑","originalKeyword":"氯氧化锑"},{"id":"187dc47e-8b52-4ab5-8298-60c875369ac9","keyword":"Sb4O5Cl2","originalKeyword":"Sb4O5Cl2"},{"id":"dbf59ba4-be7f-4078-ba13-a81085d64dcf","keyword":"电化学","originalKeyword":"电化学"},{"id":"02c43b17-a031-40af-9208-ab8f5adfb123","keyword":"制备","originalKeyword":"制备"}],"language":"zh","publisherId":"yyhx200702024","title":"电化学法制备氯氧化锑Sb4O5Cl2","volume":"24","year":"2007"},{"abstractinfo":"以二肽Pro-Trp为催化剂,2,3,4,5,6,6-六氯-2,4-环己二烯-1-酮为氯化剂,离子液体Zn[CO(NH2)2]3Cl2为溶剂,在N-甲基吗啉(NMM)存在下,各种醛能够高收率、较高立体选择性地完成羰基α-卤代反应,目标产物的产率可达到95％,对映选择性可达92％ ee.该方法具有操作简便、离子液体和催化剂可重复使用的优点.","authors":[{"authorName":"张宝华","id":"93dbf687-a5c7-4dcd-bf07-04967e1eaa29","originalAuthorName":"张宝华"},{"authorName":"史兰香","id":"c09b359e-1007-4e20-9e4a-ceef85c6625a","originalAuthorName":"史兰香"},{"authorName":"刘胜宝","id":"60a79247-f58e-4541-adf0-5fb466150ecd","originalAuthorName":"刘胜宝"}],"doi":"10.11944/j.issn.1000-0518.2015.07.140383","fpage":"743","id":"eebe4f2f-7e3a-4e8a-90a6-3d944883efaa","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"be44e0fb-64fb-4907-8299-6827672a11c6","keyword":"六氯-环己二烯-酮","originalKeyword":"六氯-环己二烯-酮"},{"id":"e245f7d7-21ba-4904-b507-fc8eb47acef6","keyword":"离子液体","originalKeyword":"离子液体"},{"id":"ca42683d-06de-431b-a4b9-2f5ef8a667b0","keyword":"二肽","originalKeyword":"二肽"},{"id":"6a5fd386-71ec-4543-9c61-719044b2577d","keyword":"氯化","originalKeyword":"氯化"},{"id":"0366adc0-8be9-4ae1-88cc-ac86638c1ff9","keyword":"醛","originalKeyword":"醛"}],"language":"zh","publisherId":"yyhx201507002","title":"离子液体Zn[CO(NH2)2]3Cl2介质中二肽催化醛的不对称α-氯代反应","volume":"32","year":"2015"},{"abstractinfo":"以MgO修饰的SBA-15为载体,采用浸渍法制备了负载β-Mg2V2O7,催化剂,并运用X射线衍射、拉曼光谱、紫外-可见漫反射光谱和H2程序升温还原等技术对催化剂V中心的结构和还原性能进行了表征.结果表明,β-Mg2V2O7具有与α-Mg2V2O7相同的结构单元,但其催化丙烷氧化脱氢(ODH)反应的初始活性和初始选择性均低于后者.与体相β-Mg2V2O7相比,负载的β-Mg2V2O7上V中心分散度以及丙烷ODH反应活性和选择件更高,520℃时丙烷ODH反应的仞始活性提高了约20倍,丙烯仞始选择性也从休相的88.3%提高到94.1%,接近于α-Mg2V2O7(94.6%),并且在20%的丙烷转化率时也表现出相似的规律.这与表征催化剂选择性的两个木征动力学参数k1k2(丙炕初级ODH和燃烧反应速率常数之比)和k3k1(次级丙烯燃烧和初级丙烷ODH反应速率常数之比)反映出的规律一致.这些对体相和负载的Mg2V2O7催化剂催化丙烷ODH反应木征特性的认识将有助于设计合成更高效的Mg-V-O催化剂,如基于α-Mg2V2O7结构的高分散催化剂,以获得更高的内烷ODH反应活性和选择性.","authors":[{"authorName":"张胜红","id":"ec56dbc3-1983-4752-8e22-a31a32a3d15c","originalAuthorName":"张胜红"},{"authorName":"张鸿鹏","id":"5f7b2980-c3b1-4eb6-ba89-b231c4c20f7d","originalAuthorName":"张鸿鹏"},{"authorName":"孙吉莹","id":"7b3ed1aa-b5ce-46b5-90bf-edbcfafcca76","originalAuthorName":"孙吉莹"},{"authorName":"刘海超","id":"7f85f2ae-fa5b-4e28-a5f7-7652dff78ded","originalAuthorName":"刘海超"}],"doi":"10.3724/SP.J.1088.2010.00451","fpage":"1374","id":"be8f5d96-50fa-4e4b-b400-810c5402cab8","issue":"11","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"2fab550b-870b-44fb-81f6-ce6036ef659f","keyword":"丙烷","originalKeyword":"丙烷"},{"id":"7511e90e-4c5f-42b2-b4a0-7ec1112bf755","keyword":"丙烯","originalKeyword":"丙烯"},{"id":"d86ec49c-f596-4c7c-be07-2ee2e3515740","keyword":"氧化脱氢","originalKeyword":"氧化脱氢"},{"id":"82b934f8-0002-45b1-b7b3-dca4c624e1c4","keyword":"焦钒酸镁","originalKeyword":"焦钒酸镁"},{"id":"6617b07d-7533-4ea6-89c5-2a95abf9d334","keyword":"负载型催化剂","originalKeyword":"负载型催化剂"}],"language":"zh","publisherId":"cuihuaxb201011012","title":"SBA-15负载β-Mg2V2O7催化剂的制备及其催化丙烷选择氧化脱氢的性能","volume":"31","year":"2010"},{"abstractinfo":"采用K3PO4×3H2O修饰的Pd/C为催化剂实现了取代四氢异喹啉高选择性部分脱氢,并成功地避免了当量有害氧化剂的使用。多相催化剂Pd/C对四氢异喹啉化合物具有催化脱氢活性,但反应选择性较差,同时产生完全脱氢的芳构化产物异喹啉。而K3PO4×3H2O修饰的Pd/C催化剂能有效提高脱氢反应的化学选择性,在最优条件下可获得最高89%的分离收率。这为取代3,4-二氢异喹啉的合成提供了一种简便、高原子经济性和高化学选择性的反应途径。此外,该多相催化剂可回收循环使用多次,且活性和选择性基本保持不变。","authors":[{"authorName":"姬悦","id":"81d2dbdf-021c-4f1b-b889-8cc519ed66b1","originalAuthorName":"姬悦"},{"authorName":"陈木旺","id":"a53333dc-7879-44fa-a36f-6c4bf6ef308c","originalAuthorName":"陈木旺"},{"authorName":"时磊","id":"f9820f28-80f6-401c-a3d8-d251edec82c5","originalAuthorName":"时磊"},{"authorName":"周永贵","id":"e218159a-8e0c-4098-bc2a-003976cbd790","originalAuthorName":"周永贵"}],"doi":"10.1016/S1872-2067(14)60243-6","fpage":"33","id":"d2cca54c-3ed6-4e37-a37a-1c7749b18bf5","issue":"1","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"48903b8e-e040-4925-aec0-96d7127c325b","keyword":"钯碳","originalKeyword":"钯碳"},{"id":"2c357e10-88a8-4e7c-b7ef-c27169460ceb","keyword":"部分脱氢","originalKeyword":"部分脱氢"},{"id":"d70bf932-9532-43ff-9811-2feece1275bc","keyword":"四氢异喹啉","originalKeyword":"四氢异喹啉"},{"id":"edbfe269-a697-4cef-8819-785c90e43312","keyword":"亚胺","originalKeyword":"亚胺"},{"id":"273faf91-eb5e-41d5-b24f-fa432ae2da34","keyword":"脱氢芳构化","originalKeyword":"脱氢芳构化"}],"language":"zh","publisherId":"cuihuaxb201501009","title":"Pd/C促进的四氢异喹啉高选择性部分脱氢","volume":"","year":"2015"}],"totalpage":8817,"totalrecord":88162}