用液化石油气作碳源、炭毡作增强体,在坯体中埋置导电层产生温度场和电磁场梯度,在自行设计的多元耦合物理场CVI炉中制备炭/炭(C/C)复合材料,并就沉积温度、压力、碳源气体浓度等工艺条件对增密速度和材料结构的影响作了探讨性研究.采用偏光显微镜研究了沉积炭的显微结构.研究表明,多元耦合物理场CVI工艺增密速度快,初始密度为0.2g/cm3,尺寸为260mm×60mm×20mm的坯体,在920℃、3kPa、碳源浓度45%的条件下沉积20h,试样的密度达到1.71 g/cm3;在960℃、0.1kPa、碳源浓度45%的条件下,可获得结构一致的粗糙层结构(RL)热解炭.
参考文献
[1] | FitzerE.Thefutureofcarbon-carboncomposites[J].CARBON,1987(25):163. |
[2] | uckleyJD;Edie D D.Carbon-carbon Materials and composites[M].ParkRidgeNJ:NoyesPublication,1993 |
[3] | uckleyJD .Carbon-carbonoverview[J].Ceramic Bulletin,1988,67(02):364. |
[4] | Granoff;Pierson H O;Schuster D M.Theeffectofchemicalvapordepositionconditionsonthepropertiesofcarboncarboncomposites[J].CARBON,1973(11):177. |
[5] | TangZhonghua;Zou Zhiqiang;Xiong Jie .Effectofinfiltrationconditionsondensificationbehaviorofcarbon/carboncompositespreparedbydirectionalflowthermalgradientCVIprocess[J].CARBON,2003,41(14):2703. |
[6] | HoudayerM;Spitz J;Tran Van D .Process for the densification of a porous structure[P].US:4472454,1984. |
[7] | 孙万昌,李贺军,陈三平,张守阳,李克智.CLVI制备C/C复合材料的微观结构及力学性能研究[J].无机材料学报,2003(01):121-128. |
[8] | JohnOforiY;Stratis V Sotirchos .Inverstigationofthepotentialofforced-flowchemicalvaporinfiltration[J].Journal of the Electrochemical Society,1997,144(01):264. |
[9] | Jeong HJ.;Lee JD.;Park JO.;Park HD. .DENSIFICATION OF CARBON/CARBON COMPOSITES BY PULSE CHEMICAL VAPOR INFILTRATION[J].Carbon: An International Journal Sponsored by the American Carbon Society,1996(3):417-421. |
[10] | 巩前明,黄启忠,黄伯云,吴凤秋,陈腾飞,张福勤.炭化压力对沥青成焦形貌及航空刹车用C/C复合材料浸渍增密效果的影响[J].新型炭材料,2002(02):23-28. |
[11] | Zhang WG.;Hu ZJ.;Huttinger KJ. .Chemical vapor infiltration of carbon fiber felt: optimization of densification and carbon microstructure[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(14):2529-2545. |
[12] | 谢志勇;黄启忠;苏哲安 等.多元耦合物理场作用下化学气相沉积快速制备炭/炭复合材料的方法[P].CN:200410029034.X,2004. |
[13] | Granoff;Pierson H O;Schuster D M .Theeffectofchemicalvapordepositionconditionsonthepropertiesofcarboncarboncomposites[J].CARBON,1973,11:177. |
[14] | AgnesOerlin .Pyrocarbons[J].Carbon,2002,40:7. |
[15] | Yung Joon Jung;Bingqing Wei;John Nugent;Pulickel M. Ajayan .Controlling growth of carbon microtrees[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(14):2195-2201. |
[16] | HuZJ;Zhang W G;Huttinger K J et al.Influenceofpressure,temperatureandsurfacearea/volumeratioonthetextureofpyrolyticcarbondepositedfrommethane[J].CARBON,2003,41:749. |
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