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以麦秸秆粉为填充材料(质量分数50%),以聚丙烯(PP)膜为基体材料,采用混炼模压成型制备麦秸秆/PP木塑复合材料,对其进行紫外线加速老化实验,对比研究不同填充材料的木塑复合材料老化前后的力学性能和颜色变化,用FTIR分析探讨了复合材料老化机制,用SEM观察其表面微观形貌.结果表明,紫外线加速老化会导致麦秸秆/PP复合材料力学性能降低,当老化时间小于960 h时,麦秸秆/PP木塑复合材料弯曲强度、拉伸强度下降幅度较小,老化时间大于960 h时,力学性能下降幅度较大,材料褪色明显;老化1200 h其弯曲强度、拉伸强度、冲击强度分别下降67.2%、47.89%、32.41%;麦秸秆纤维中羟基加速了PP的紫外光降解,最终材料表面出现明显裂纹,部分纤维剥落并伴随有PP粉化现象.

参考文献

[1] Tamrakar S,Lopez-Anido R A,Kiziltas A,et al.Time and temperature dependent response of a wood-polypropylene composite[J].Composites Part A:Applied Science and Manufacturing,2011,42(7):834-842.
[2] 李晶晶,李大纲,郭 勇,等.环境对尿不湿边角料/聚乙烯复合材料的材色影响[J].塑料工业,2010,38(9):72-75.Li Jingjing,Li Dagang,Guo Yong,et al.Effect of environment on color of the diapers scrap/PE composite[J].China Plastics Industry,2010,38(9):72-75.
[3] 王伟宏,王清文,张征明.稻壳/聚乙烯复合材的自然老化与紫外光加速老化[J].林业科学,2008,44(8):90-94.Wang Weihong,Wang Qingwen,Zhang Zhengming.Natural weathering and accelerated UV weathering of rice-hull polyethylene composite[J].Scientia Silvae Sinicae,2008,44(8):90-94.
[4] 周吓星,林巧佳,陈礼辉.自然气候老化对木塑复合材料蠕变性能的影响[J].福州大学学报:自然科学版,2011(1):96-100.Zhou Xiaxing,Lin Qiaojia,Chen Lihui.Impact of the natural weathering on the creep behavior of wood-plastic composite[J].Journal of Fuzhou University:Natural Science Edition,2011(1):96-100.
[5] 周箭,张启龙,杨辉,等.抗紫外PVDF基木塑复合材料的热分析[J].材料科学与工程学报,2009,27(6):845-849.Zhou Jian,Zhang Qilong,Yang Hui,et al.Thermal analysis of anti-ultraviolet poly (vinylidene fluoride)/wood flour composites[J].Journal of Materials Science and Engineering,2009,27(6):845-849.
[6] 王林娜,蔡建臣,薛平.木塑复合材料加速老化性能的研究[J].工程塑料应用,2010,38(2):63-66.Wang Linna,Cai Jianchen,Xue Ping.Study on accelerated aging properties of wood plastic composite[J].Engineering Plastics Application,2010,38(2):63-66.
[7] Stark N,Clemons C.Durability of wood and polyethylene composite lumber[R].Madison:USDA Forest Serviee,2003.
[8] Rangaraj S V,Smith L V.Effect of moisture on the durability of a wood/thermoplastic composite[J].Journal of Thermoplastic Composite Materials,2000,13(2):140-161.
[9] Stark N M,Matuana L M.Ultraviolet weathering of photostabilized wood-flour-filled high-density polyethylene composites[J].Journal of Applied Polymer Science,2003,90(10):2609-2617.
[10] Dominkovics Z,Danyadi L,Pukanszky B.Surface modification of wood flour and its effect on the properties of PP/wood composites[J].Composites Part A:Applied Science and Manufacturing,2007,38(8):1893-1901.
[11] Espert A,Las Heras de L A,Karlsson S.Emission of possible odourous low molecular weight compounds in recycled biofibre/polypropylene composites monitored by head space SPME-GC-MS[J].Polymer Degradation and Stability,2005,90(3):555-562.
[12] Falk R H,Lundin T,Felton C.The effects of weathering on wood-thermoplastics composites intended for outdoor applications[C]//Forest Products Society.Proceedings of the 2nd Annual Conference on Durability and Disaster Mitigation in Wood-Frame Housing.Madison:FPS,2000:175-179.
[13] 赵永生,王克俭,朱复华,等.蒙脱土/硅烷改性木粉/PVC复合材料[J3.复合材料学报,2007,24(3):63-71.Zhao Yongsheng,Wang Kejian,Zhu Fuhua,et al.Properties of montmorillonite/silane-modified wood flour/PVC composites[J].Acta Materiae Compositae Sinica,2007,24(3):63-71.
[14] 何春霞,顾红艳,薛盘芳.四种植物纤维粉/聚丙烯复合材料应用性能[J].农业工程学报,2010,26(2):381-384.He Chunxia,Gu Hongyan,Xue Panfang.Performances of polypropylene composite material filled with four kinds of plant fiber powders[J].Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE),2010,26(2):381-384.
[15] Fabiyi J S,McDonald A G.Effect of wood species on property and weathering performance of wood plastic composites[J].Composites Part A:Applied Science and Manufacturing,2010,41(10):1434-1440.
[16] 于旻,何春霞,刘军军,等.不同表面处理麦秸秆对木塑复合材料性能的影响[J].农业工程学报,2012,28(9):171-177.Yu Min,He Chunxia,Liu Junjun,et al.Effects of different surface treatment for wheat straw on performances of woodplastic composites[J].Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE),2012,28(9):171-177.
[17] 李永峰,刘一星,于海鹏,等.甲基丙烯酸缩水甘油酯改善木塑复合材料性能[J].复合材料学报,2009,26(5):1-7.Li Yongfeng,Liu Yixing,Yu Haipeng,et al.Property improvement of wood polymer composites with glycidyl methacrylate[J].Acta Materiae Compositae Sinica,2009,26(5):1-7.
[18] 关苏军,万春风,汪丽娜,等.玄武岩纤维增强木塑复合材料的力学性能[J].复合材料学报,2011,28(5):162-167.Guan Sujun,Wan chunfeng,Wang Lina,et al.Mechanical properties of basalt fiber reinforced wood-plastic composites[J].Acta Materiae Compositae Sinica,2011,28(5):162-167.
[19] Bengtsson M,Gatenholm P,Oksman K.The effect of crosslinking on the properties of polyelene/wood flour composites[J].Composites Science and Technology,2005,65(10):1468-1479.
[20] 何春霞,侯人鸾,薛娇,等.不同模压成型条件下PP木塑复合材料性能研究[J].农业工程学报,2012,28(15):145-150.He Chunxia,Hou Renluan,Xue Jiao,et al.Study on performances of PP wood-plastic composites with different processing methods[J].Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE),2012,28(15):145-150.
[21] 侯人鸾,何春霞,于 旻.稻秸秆/玉米淀粉胶复合材料的制备及性能[J].合成材料老化与应用,2012,41(2):1-5.Hou Renluan,He Chunxia,Yu Min.Preparation and properties of rice straw/cornstarch adhesive composite[J].Synthetic Materials Aging and Application,2012,41(2):1-5.
[22] Fabiyi J S.Chemistry of wood plastic composite weathing[D].Idaho:University of Idaho,2007.
[23] 杨淑惠.植物纤维化学[M].北京:中国轻工业出版社,2001.Yang Shuhui.Plant fiber chemistry[M].Beijing:China Light Industry Press,2001.
[24] 国家技术监督局.GB/T 16422.3-1997塑料实验室光源暴露试验方法Ⅲ:荧光紫外灯[S].北京:中国标准出版社,1997.State Quality Supervision Bureau.GB/T 16422.3-1997Plastics-Methods of exposure to laboratory light sources Ⅲ:Fluorescent UV lamps[S].Beijing:China Standard Press,1997.
[25] 中国国家标准化管理委员会.GB/T 1040.4-2006塑料拉伸性能的测定Ⅳ:各向同性和正交各向异性纤维增强复合材料的试验条件[S].北京:中国标准出版社,2006.Standardization Administration of the People's Republic of China.GB/T 1040.4-2006 Plastics Determination of tensile properties Ⅳ:Test conditions for isotropic and orthotropic fibre-reinforces plastic composites[S].Beijing:China Standard Press,2006.
[26] 中国国家标准化管理委员会.GB/T 9341-2008塑料弯曲性能的测定[S].北京:中国标准出版社,2008.Standardization Administration of the People's Republic of China.GB/T 9341-2008 Plastics-Determination of flexural properties[S].Beiiing:China Standard Press,2008.
[27] 中国国家标准化管理委员会.GB/T 1043.1-2008塑料简支梁冲击性能的测定Ⅰ:非仪器化冲击试验[S].北京:中国标准出版社,2008.Standardization Administration of the People's Republic of China.GB/T 1043.1-2008 Plastics-Determination of charpy impact properties Ⅰ:Non-instrumented impact test[S].Beijing:China Standard Press,2008.
[28] 党文杰.紫外加速老化对木纤维聚丙烯复合材料性能的影响[D].黑龙江:东北林业大学,2007.Dang Wenjie.Influence of ultraviolet accelerated weathering on the properties of wood fiber/polypropylene composites[D].Heilongjiang:Northeast Forestry University,2007.
[29] Selden R,Nystrom B,Langstrom R.UV aging of polypropylene/wood-fiber composites[J].Polymer Composites,2004,25(5):543-553.
[30] 石光,秦炜,林少全,等.木塑复合材料老化性能研究进展[J].包装工程,2009,30(1):120-123.Shi Guang,Qin Wei,Lin Shaoquan,et al.Research progresses of aging performance of wood-plastic composite[J].Packaging Engineering,2009,30(1):120-123.
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