CuO/γ-Al2O3催化吸附剂脱硝性能研究

工程热物理学报 , 2007, 28(z2): 225-228.

CuO/γ-Al2O3催化吸附剂脱硝性能研究

赵清森 ^1, , 向军 ^2, , 石金明 ^3, , 陈伟 ^4, , 胡松 ^5, , 孙路石 ^6, , 张军营 ^7,

1.华中科技大学煤燃烧国家重点实验室,湖北,武汉,430074

2.华中科技大学煤燃烧国家重点实验室,湖北,武汉,430074

3.华中科技大学煤燃烧国家重点实验室,湖北,武汉,430074

4.华中科技大学煤燃烧国家重点实验室,湖北,武汉,430074

5.华中科技大学煤燃烧国家重点实验室,湖北,武汉,430074

6.华中科技大学煤燃烧国家重点实验室,湖北,武汉,430074

7.华中科技大学煤燃烧国家重点实验室,湖北,武汉,430074

基金项目: 国家重点基础研究发展计划(973计划)(2006CB200304) 教育部科学技术研究项目(306012)

关键词： CuO/γ-Al2O3 , 溶胶-凝胶法 , 烟气 , 脱硝

EXPERIMENTAL RESEARCH OF ALUMINA SUPPORTED COPPER OXIDE SORBENT FOR FLUE GAS DENITRATION

本文采用溶胶-凝胶法制备CuO/γ-Al2O3催化吸附剂颗粒.分析表明:SO2的存在可以提高CuO/γ-Al2O3催化吸附剂的脱硝活性,SO2存在条件下,CuO/γ-Al2O3催化吸附剂的脱硝活性在载铜量8wt%时达到最高,达到95.7%.载铜量太高会使单位质量催化剂NO脱除率降低.在350℃时,硫酸盐化和未硫酸盐化的8wt%Cu催化吸附剂NO脱除率达到最高.NH3/NO摩尔比在1～1.2之间时,CuO/γ-Al2O3催化吸附剂的脱硝活性较高.

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