采用微弧氧化技术在镁锂合金表面制备了陶瓷膜,通过扫描电镜、X射线能谱分析、动电位极化曲线等测试技术研究了陶瓷膜的表面和截面形貌、元素组成以及耐蚀性能.采用在基本电解液里添加植酸的方法将其引入陶瓷膜,并讨论植酸质量浓度对成膜过程和陶瓷膜性能的影响.研究结果表明:陶瓷膜厚度随电解液中植酸浓度的增加而变大,膜层表面形貌逐渐改善;膜层中成功地引入了碳、磷元素,随植酸浓度增加,膜层中的碳、磷元素含量增大,镁元素含量降低;植酸的质量浓度为4g/L时所制备的陶瓷膜均匀细致,耐腐蚀性能最好.
参考文献
[1] | 乐启炽,崔建忠,李红斌,张新建.Mg-Li合金研究最新进展及其应用[J].材料导报,2003(12):1-4,8. |
[2] | Song Dalei;Jing Xiaoyan;Jun Wanga et al.Corrosion resistant ZSM-5 zeolite coatings formed on Mg-Li alloy by hotpressing[J].Corrosion Science,2011,53:1732. |
[3] | Chang Limin .Growth regularity of ceramic coating on magnesium alloy by plasma electrolytic oxidation[J].Journal of Alloys and Compounds,2009,468:462. |
[4] | 徐用军,李康,姜兆华,姚忠平,张密林.镁锂合金表面陶瓷膜的制备工艺及耐蚀性能[J].材料科学与工艺,2010(01):133-136. |
[5] | Shi Lingling;Xu Yongjun;Li Kang;Yao Zhongping;Wu Songquan .Review Effect of additives on structure and corrosion resistance of ceramic coatings on Mg–Li alloy by micro-arc oxidation[J].Current applied physics: the official journal of the Korean Physical Society,2010(3):719-723. |
[6] | 陈东初,吴飞鹏,李文芳.植酸在镁合金表面处理中的应用研究[J].材料保护,2006(11):24-26. |
[7] | Gao Lili;Zhang Chunhong;Zhang Milin et al.Phytic acid conversion coating on Mg-Li alloy[J].Journal of Alloys and Compounds,2009,485:789. |
[8] | Pan Fusheng;Yang Xu;Zhang Dingfei .Chemical nature of phytic acid conversion coating on AZ61 magnesium alloy[J].Applied Surface Science,2009,255:8363. |
[9] | Cui Xiufang;Li Qingfen;Li Ying et al.Microstructure and corrosion resistance of phytic acid conversion coatings for magnesium alloy[J].Applied Surface Science,2008,255:2098. |
[10] | Guo HF;An MZ .Growth of ceramic coatings on AZ91D magnesium alloys by micro-arc oxidation in aluminate-fluoride solutions and evaluation of corrosion resistance[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2005(1/3):229-238. |
[11] | S. J. Xia;R. Yue;R. G. Rateick Jr. .Electrochemical Studies of AC/DC Anodized Mg Alloy in NaCl Solution[J].Journal of the Electrochemical Society,2004(3):B179-B187. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%