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以三维针刺碳毡作为预制体,先采用树脂单向加压浸渍-热解工艺制备出C/C多孔体,再通过反应熔体浸渗法获得C/SiC复合材料.重点研究了C/C多孔体的高温热处理对C/SiC复合材料结构和力学性能的影响.结果表明,C/C多孔体的高温热处理不会改变C/SiC复合材料的相组成,但可使复合材料中的SiC含量提高,C含量降低;高温热处理有利于熔融Si浸渗,使复合材料致密度增大,孔隙率降低,从而使其弯曲断裂强度提高约28%;高温热处理还可使纤维-基体界面结合强度降低,改善复合材料的断裂韧性.

参考文献

[1] Laifei Cheng;Yongdong Xu;Litong Zhang;Xingang Luan .Corrosion of a 3D-C/SiC composite in salt vapor environments[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(6):877-882.
[2] Xiaowei Yin;Laifei Cheng;Litong Zhang;Yongdong Xu .Thermal shock behavior of 3-dimensional C/SiC composite[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(6):905-910.
[3] Schrnidt S et al.Advanced ceramic matrix composite materials for current and future propulsion technology applications[J].Acta Astronautica,2004,55(3-9):409.
[4] Vaidyaraman S.C/SiC material evaluation for aircraft brake applications[A].Munich,Germany,2001:802.
[5] Walter Krenkel .C/C-SIC COMPOSITES FOR HOT STRUCTURES AND ADVANCED FRICTION SYSTEMS[J].Ceramic Engineering and Science Proceedings,2003(4):583-592.
[6] 尹立,赵东林,刘辉,迟伟东,沈曾民.石墨化处理对三维针刺C/C复合材料力学性能的影响[J].材料热处理学报,2011(02):10-15.
[7] 李伟,李贺军,张守阳,魏建锋,王杰,李照谦.石墨化处理对双层热解炭基2DC/C复合材料微观结构的影响[J].新型炭材料,2011(05):328-334.
[8] 于守泉,张伟刚.热处理温度对热解炭及炭/炭复合材料力学性能的影响[J].无机材料学报,2010(03):315-320.
[9] 周红英,舒武炳,刘建军,程文,邹武,黄寒星.高温热处理与C/C复合材料性能关系研究[J].固体火箭技术,2007(01):68-71,79.
[10] Yanzhi Cai;Yongdong Xu;Bin Li .Low-cost preparation and frictional behaviour of a three-dimensional needled carbon/silicon carbide composite[J].Journal of the European Ceramic Society,2009(3):497-503.
[11] Frie M;Krenkel W;Brandt R.Influence of process parameters on the thermophysical properties of C/C-SiC[A].Weinheim:Federal Republic of Germany,2001:328.
[12] 袁义云,宋迎东,孙志刚.孔隙率对多孔陶瓷材料失效强度的影响[J].航空动力学报,2008(09):1623-1627.
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