综述了近年来低维钨氧化物的研究动态,简要介绍了制备低维钨氧化物的方法和特点.评价以这些材料作为燃料电池阳极催化剂载体的铂基催化剂的催化活性及稳定性,并与目前普遍采用的商业碳质载铂(Pt/C)催化剂进行比较.最后,展望了此类载体材料的发展方向.
参考文献
[1] | 申泮文;车云霞;罗裕基.无机化学丛书第八卷[M].北京:科学出版社,2011:407. |
[2] | Migas D B;Shaposhnikov V L;Rodin V N et al.Tungsten oxides.[.Effects of oxygen vacancies and doping on electronic and optical properties of different phases of WO3[J].Journal of Applied Physics,2010,108:093713. |
[3] | Migas D B;Shaposhnikov V L;Borisenko V E et al.Tungsten oxides.Ⅱ.The metallic nature of Magnéli phases[J].Journal of Applied Physics,2010,108:093714. |
[4] | Antolini, E.;Gonzalez, E. R. .Ceramic materials as supports for low-temperature fuel cell catalysts[J].Solid state ionics,2009(9/10):746-763. |
[5] | Pfeifer J;Badaljan E;Tekula-Buxbaum P et al.Growth and morphology of W18O49 crystals produced by microwave decomposition of ammonium paratungstate[J].Journal of Crystal Growth,1996,169:727. |
[6] | Baeck S H;Choi K S;Jaramillo T F et al.Enhancement of photocatalytic and electrochromic properties of electrochemically fabricated mesoporous WO3 thin flims[J].Advanced Materials,2003(15):1269. |
[7] | Deb SK .Opportunities and challenges in science and technology of WO3 for electrochromic and related applications[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2008(2):245-258. |
[8] | Clara Santato;Marek Odziemkowski;Martine Ulmann;Jan Augustynski .Crystallographically Oriented Mesoporous WO_3 Film: Synthesis Characterization , and Applications[J].Journal of the American Chemical Society,2001(43):10639-10649. |
[9] | LiXL;LouT J;SunXM et al.Highly sensitive WO3 hollow-sphere gas sensors[J].Inorganic Chemistry,2004,43:5442. |
[10] | Granqvist CG. .Electrochromic tungsten oxide films: Review of progress 1993-1998 [Review][J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2000(3):201-262. |
[11] | Turyan I.;Orel B.;Saraidorov T.;Reisfeld R.;Mandler D.;Krasovec UO. ."Writing-reading-erasing" on tungsten oxide films using the scanning electrochemical microscope[J].Advanced Materials,2000(5):330-333. |
[12] | Li X Z;Li F B;Yang C L et al.Photocatalytic activity of WOx-TiO2 under visible light irradiation[J].Journal of Photochemistry and Photobiology A:Chemistry,2001,141:209. |
[13] | Hu WB.;Hsu WK.;Chang BH.;Terrones M.;Grobert N.;Terrones H. Hare JP.;Kroto HW.;Walton DRM.;Zhu YQ. .Generation of hollow crystalline tungsten oxide fibres[J].Applied physics, A. Materials science & processing,2000(2):231-233. |
[14] | Zhou, J;Ding, Y;Deng, SZ;Gong, L;Xu, NS;Wang, ZL .Three-dimensional tungsten oxide nanowire networks[J].Advanced Materials,2005(17):2107-2109. |
[15] | Shi SL;Xue XY;Feng P;Liu YG;Zhao H;Wang TH .Low-temperature synthesis and electrical transport properties of W18O49 nanowires[J].Journal of Crystal Growth,2008(2):462-466. |
[16] | Li YB.;Bando Y.;Golberg D.;Kurashima K. .WO3 nanorods/nanobelts synthesized via physical vapor deposition process[J].Chemical Physics Letters,2003(1/2):214-218. |
[17] | Yubao Li;Yoshio Bando;Dmitri Golberg .Quasi-Aligned Single-Crystalline W_(18)O_(49) Nanotubes and Nanowires[J].Advanced Materials,2003(15):1294-1296. |
[18] | Liu ZW.;Bando Y.;Tang CC. .Synthesis of tungsten oxide nanowires[J].Chemical Physics Letters,2003(1/2):179-182. |
[19] | Hong K Q;Yiu W C;Wu H S et al.Asimplemethod for growing high quantity tungsten-oxide nanoribbons under moist conditions[J].Nanotechnology,2005,16:1608. |
[20] | Raman Ganesan;Jae Sung Lee .An electrocatalyst for methanol oxidation based on tungsten trioxide microspheres and platinum[J].Journal of Power Sources,2006(1):217-221. |
[21] | Rajeswari J;Viswanathan B;Varadarajan TK .Tungsten trioxide nanorods as supports for platinum in methanol oxidation[J].Materials Chemistry and Physics,2007(2/3):168-174. |
[22] | Gado P;Mageneli A .Shear structure of the wolfram oxide WO2.95[J].Acta Chemica Scandinavica,1965,19(06):1514. |
[23] | Venables D;Brown M E .Reduction of tungsten oxides with carbon.Part 1:Thermal analyses[J].Thermochimica Acta,1996,282-283:251. |
[24] | Venables D;Brown M E .Reduction of tungsten oxides with carbon.Part 2:Tube furnace experiments[J].Thermochimica Acta,1996,282-283:256. |
[25] | Venables DS.;Brown ME. .REDUCTION OF TUNGSTEN OXIDES WITH CARBON MONOXIDE[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,1997(1/2):131-140. |
[26] | Venables DS.;Brown ME. .REDUCTION OF TUNGSTEN OXIDES WITH HYDROGEN AND WITH HYDROGEN AND CARBON[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,1996(2):361-382. |
[27] | Aird A;Domeneghetti M C;Mazzi F et al.Sheet superconductity in WO3-x:Crystal structure of the tetragnal mattrix[J].Journal of Physics:Condensed Matter,1998,10:L569. |
[28] | ZhuY Q;Hu W B;Hsu W K et al.Tungsten oxide treelike structures[J].Chemical Physics Letters,1999,309:327. |
[29] | Ganesan R;Perelshtein I;Gedanken A .Biotemplated synthesis of single-crystalline W18O49@Ccore-shell nanorod and its capacitance properties[J].Journal of Physical Chemistry C,2008,112:1913. |
[30] | Cui X Z;Shi J L;Chen H R et al.Platinum/mesoporous WO3 as a carbonfree electrocatalyst with enhanced electrochemical activity for methanol oxidation[J].Journal of Physical Chemistry B,2008,112:12024. |
[31] | Jeon S;Yong KJ .Direct synthesis of W18O49 nanorods from W2N film by thermal annealing[J].Nanotechnology,2007(24):45602-1-45602-7-0. |
[32] | McLeod E J;Birss V I .Sol-gel derived WOx and WOx/Pt films for direct methanol fuel cell catalyst applications[J].Electrochimica Acta,2005,51:684. |
[33] | Li XL.;Liu JF.;Li YD. .Large-scale synthesis of tungsten oxide nanowires with high aspect ratio[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2003(3):921-924. |
[34] | Seo J W;Jun Y W;Ko S J et al.In situ one-pot synthesis of 1-dimensional transition metal oxide nanocrystals[J].Journal of Physical Chemistry B,2005,109:5389. |
[35] | Lee K;Seo W S;Park J T .Synthesis and optical properties of colloidal tungsten oxide nanorods[J].Journal of the American Chemical Society,2003,125:3408. |
[36] | Lou XW.;Zeng HC. .An inorganic route for controlled synthesis of W18O49 nanorods and nanofibers in solution[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2003(20):6169-6171. |
[37] | Liu Z M;Zhang H Y;Huang C L .et ak One-pot solvothermal method to synthesize platinum/W18O49 ultrafine nanowires and their catalytic performance[J].Journal of Materials Chemistry,2012,22:3354. |
[38] | T. Maiyalagan;B. Viswanathan .Catalytic activity of platinum/tungsten oxide nanorod electrodes towards electro-oxidation of methanol[J].Journal of Power Sources,2008(2):789-793. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%