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采用固相反应法合成Mg0.7Zn0.3TiO3(M7Z3T)粉体作为凝胶注模成型的原料,研究了分散剂(PAA-NH4)加入量、pH值、固相含量、单体(AM)浓度和单体与交联剂(MBAM)质量比对浆料流变性的影响.结果表明:当浆料pH值为10,分散剂(PAA-NH4)加入量为0.7wt%时,固相含量为52vol%,M7Z3T浆料的起始粘度为0.459Pa·s.预混液中单体含量为10wt%,交联剂与单体质量比为20∶1,引发剂(APS)加入量为1wt%,固化温度为60℃的条件下,采用凝胶注模成型制备出了抗弯强度为24.47 MPa的M723T生坯.

参考文献

[1] Anatolii Belous;Oleg Ovchar;Dmitrii Durylin .Microwave composite dielectrics based on magnesium titanates[J].Journal of the European Ceramic Society,2007(8/9):2963-2966.
[2] Cheng-Liang Huang;Chun-Hsu Shen;Chung-Long Pan .Characterization and dielectric behavior of V_2O_5-doped MgTiO_3-CaTiO_3 ceramic system at microwave frequency[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2007(1/3):91-96.
[3] 李亮,沈春英,丘泰.(Mg1-xZnx)TiO3系陶瓷微波介电性能的研究[J].电子元件与材料,2008(10):38-40.
[4] 吴甲民,吕文中,梁军,汪小红.水基凝胶注模成型工艺制备0.9Al2O3-0.1TiO2陶瓷的微波介电性能[J].无机材料学报,2011(01):102-106.
[5] Jia-Min Wu;Wen-Zhong Lu;Wen Lei;Xiao-Chuan Wang .Preparation of ZnAl_2O_4-based microwave dielectric ceramics and GPS antenna by aqueous gelcasting[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2011(9):1485-1489.
[6] 刘晓光,李国军,仝建峰,陈大明.8%Y2O3-ZrO2水基料浆的流变性质研究[J].硅酸盐学报,2003(10):923-927.
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