The rare earth-containing composite elastomer was obtained by the reaction of vinyl pyridine-SBR (PSBR) latex with rare earth alkoxides, and its thermal oxidation resistance was studied. After aging test, it is found that its retention rate of mechanical properties is far higher than that of the control sample. The results of thermogravimetric analysis show that its thermal-decomposing temperature rises largely. The analysis of oxidation mechanisms indicates that the main reasons for thermal oxidation resistance are that rare earth elements are of the utility to discontinue autoxidation chain reaction and that the formed complex structure has steric hindrance effect on oxidation.
参考文献
[1] | QU G J;LIU J J;TANG G B.Study on rare earth oxide filled polypropylene composite material[J].Polymeric materials science and engineering,1991(06):102-106. |
[2] | Yang W;WU C L;WU Z Y .Study on mixed rare earth metal oxides cross-linked chlorosulfonated polyethylene[J].Rubb Ind,1992,39(03):132-137. |
[3] | LI F P;BIAN J F;ZHANG H Y .Effect of metal (hydr) oxide on heat-resistant aging properties of fluoroether rubber[J].Rubb Ind,1998,45(05):281-284. |
[4] | SHEN J W;LIU Yue-jian;LIU Yun-ji.Effect of rare earth carboxylate on rheological performances of poly (vinyl chloride)[J].Plas Ind,1993(06):52-53. |
[5] | Zhang M;ZHANG Z B;QIU G M .Preparation and mechanical performances of rare earth-containing composite elastomer[J].中国稀土学报,2002,18(03):233-238. |
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