欢迎登录材料期刊网

材料期刊网

高级检索

The golden and ultraviolet-absorbed CeO2-TiO2 film was prepared on soda-lime glass substrate with the thickness of 2 mm via the sol-gel method. The transmission spectra in range of 200 nm-800 nm were measured, and the crystallization, the abrasion and acid resistance were also investigated. The appropriate sol contents and heat-treatment schedule were determined. The results indicate that the appropriate molar ratio of Ce/Ti was 3:5 to 5:6. The ultraviolet-absorbance ability increased with the increase of the Ce/Ti molar ratio, but when the Ce/Ti molar ratio was higher than 1.5, the homogeneity of the film was deteriorated. With the increase of heat-treatment temperature, the main wavelengths of the color of the coated glasses were equal, but the color's saturation decreased; the transmission peaks were the same, while the intensity of the peaks decreased. The roughness, abrasion and acid resistance of the film were also en hanced at the same time. The appropriate heattreatment temperature may be 340 ℃.

参考文献

[1] Yuan Yisong;Wu Bocheng;Luo Hongqi.Color Glass[M].北京:中国轻工业出版社,1987
[2] Ma Juanrong;Luo Yi;Liu Zhongwei.Application Technique in Building Glass[M].北京:化学工业出版社,2005
[3] D Camino;D Deroo;J Salardenne et al.(CeO2)x-(TiO2)1-x:Counter Clectrode Materials for Lithium Electrochromic Devices[J].Solar Energy Materials and Solar Cells,1995,39:349-366.
[4] N. Janke;A. Bieberle;R. Weissmann .Characterization of sputter-deposited WO{sub}3 and CeO{sub}(2-x) -TiO{sub}2 thin films for electrochromic applications[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2001(1):134-141.
[5] Akio Makishima;Mitsuaki ASAMI;Kenji WADA .Preparation of CeO2-TiO2 Coatings by the Sol-gel Process[J].Journal of Non-Crystalline Solids,1988,100:321-324.
[6] Takeshi Morimoto;Hiroyuki Tomonaga;Akemi Mitani .Ultraviolet ray absorbing coatings on glass for automobiles[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1999(12):61-65.
[7] Hiromichi Sakamoto;Jianbei Qiu;Akio Makishima .The preparation and properties of CeO_2-TiO_2 film by sol-gel spin-coating process[J].Science and technology of advanced materials,2003(1):69-76.
[8] F. E. Ghodsi;F. Z. Tepehan;G. G. Tepehan .Optical and electrochromic properties of sol-gel made CeO{sub}2-TiO{sub}2 thin films[J].Electrochimica Acta,1999(18):3127-3136.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%