选择性催化还原技术(SCR)是当今世界上最主流的NOx脱除技术之一,而对催化剂的开发利用是该脱硝技术的研究重点.然而目前商业使用的催化剂起活温度偏高,不能很好的适应低温烟气脱硝需求.开发低温高效、性能稳定的催化剂具有重要意义.通过实验和测试分析发现,CeO2作为载体具有较高的催化活性、热稳定性和抗烧结能力,在其它载体上掺杂CeO2可以增强催化剂的储氧能力和表面酸性,促进NH3在催化剂表面的吸附和活化,从而大幅度提高催化剂的低温脱硝活性.本文重点阐述CeO2在SCR低温脱硝催化剂中应用的研究进展,并分析CeO2在低温脱硝催化剂中的作用机理及其影响因素.
参考文献
[1] | 于国峰,韦彦斐,金瑞奔,朱虹,顾震宇,潘理黎.Mn-Ce-Co/TiO_2催化剂低温脱硝活性研究[J].环境科学学报,2012(07):1743-1749. |
[2] | 于千.国内外SCR催化剂应用概述[J].应用化工,2010(06):921-924,928. |
[3] | 徐青,郑章靖,凌长明,李军.低温选择性催化还原脱除NOx的催化剂的研究进展[J].环境污染与防治,2011(06):81-85,102. |
[4] | Zhang, D.;Du, X.;Shi, L.;Gao, R. .Shape-controlled synthesis and catalytic application of ceria nanomaterials (Review)[J].Dalton transactions: An international journal of inorganic chemistry,2012(48):14455-14475. |
[5] | The activity and characterization of CeO_2-TiO_2 catalysts prepared by the sol-gel method for selective catalytic reduction of NO with NH_3[J].Journal of hazardous materials,2010(1/3):734. |
[6] | Haidi Liu;Lianqi Wei;Renliang Yue .CrO_x-CeO2 binary oxide as a superior catalyst for NO reduction with NH3 at low temperature in presence of CO[J].Catalysis Communications,2010(9):829-833. |
[7] | Maria Casapu;Oliver Krocher;Max Mehring .Characterization of Nb-Containing MnO_x-CeO2 Catalyst for Low-Temperature Selective Catalytic Reduction of NO with NH3[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(21):9791-9801. |
[8] | Ziran Ma,Duan Weng,Xiaodong WU,Zhichun Si.Effects of WOx modification on the activity, adsorption and redox properties of CeO2 catalyst for NOx reduction with ammonia[J].环境科学学报(英文版),2012(07):1305-1316. |
[9] | Phornphimon Maitarad;Dengsong Zhang;Ruihua Gao .Combination of Experimental and Theoretical Investigations of MnO_x/Ce_(0.9)Zr_(0.1)O2 Nanorods for Selective Catalytic Reduction of NO with Ammonia[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2013(19):9999-10006. |
[10] | Dongyu Jiang;Minhua Zhang;Guiming Li.Preparation and evaluation of MnO_x-CeO2 nanospheres via a green route[J].Catalysis Communications,2012:59-63. |
[11] | Dengsong Zhang;Lei Zhang;Liyi Shi .In situ supported MnO_x-CeO_x on carbon nanotubes for the low-temperature selective catalytic reduction of NO with NH3[J].Nanoscale,2013(3):1127-1136. |
[12] | 徐海迪,邱春天,张秋林,林涛,龚茂初,陈耀强.WO3对MnOx-CeO2/ZrO2-TiO2整体式催化剂NH3选择性催化还原NOx性能的影响[J].物理化学学报,2010(09):2449-2454. |
[13] | Wei-guo Pan;Yue Zhou;Rui-tang Guo .Influence of Calcination Temperature on CeO2-CuO Catalyst for the Selective Catalytic Reduction of NO with NH3[J].Environmental Progress & Sustainable Energy,2014(2):385-389. |
[14] | 何勇,童华,童志权,黄妍,夏斌.新型CuSO4-CeO2/TS催化剂低温NH3还原NO及抗中毒性能[J].过程工程学报,2009(02):360-367. |
[15] | 赵清森,周英彪,向军,王乐乐,苏胜,胡松,孙路石.CuO-CeO2-MnOx/γ-Al2O3催化剂选择性催化还原NO[J].燃料化学学报,2009(03):360-366. |
[16] | 金瑞奔 .负载型Mn-Ce系列低温SCR脱硝催化剂制备、反应机理及抗硫性能研究[D].浙江大学,2010. |
[17] | 耿春香,刘文蓉,柴倩倩,王陈珑.Mn-Ce/TiO2低温脱硝催化剂的性能[J].化工进展,2012(06):1353-1356. |
[18] | 胡宇峰,薛建明,王小明,盛重义,廖伟平.Mn-Ce/TiO2低温选择性催化还原催化剂二氧化硫中毒及再生特性[J].工业催化,2013(04):27-33. |
[19] | SHENG Zhongyi,HU Yufeng,XUE Jiaoming,WANG Xiaoming,LIAO Weiping.SO2 poisoning and regeneration of Mn-Ce/TiO2 catalyst for low temperature NOx reduction with NH3[J].稀土学报(英文版),2012(07):676-682. |
[20] | 于国峰,顾月平,金瑞奔.Mn/TiO2和Mn-Ce/TiO2低温脱硝催化剂的抗硫性研究[J].环境科学学报,2013(08):2149-2157. |
[21] | Yanli Wang;ChuanZhang Ge;Liang Zhan .MnO_x-CeO2/Activated Carbon Honeycomb Catalyst for Selective Catalytic Reduction of NO with NH3 at Low Temperatures[J].Industrial & Engineering Chemistry Research,2012(36):11667-11673. |
[22] | Xie Wang;Yuying Zheng;Jinxian Lin.Highly dispersed Mn-Ce mixed oxides supported on carbon nanotubes for low-temperature NO reduction with NH3[J].Catalysis Communications,2013:96-99. |
[23] | Gao, S.;Chen, X.;Wang, H.;Mo, J.;Wu, Z.;Liu, Y.;Weng, X..Ceria supported on sulfated zirconia as a superacid catalyst for selective catalytic reduction of NO with NH_3[J].Journal of Colloid and Interface Science,2013:515-521. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%