研究了以乙炔为基本原料,用N2做载流气体;以纳米钻颗粒为催化剂在700~800℃常压下纳米碳管的宏观量制备.粗产品中纳米碳管的含量接近50%,而且纳米碳管缺陷很少,直而长,石墨化好.纳米碳管的形核过程是因为碳在催化剂表面分布不均匀造成的.纳米碳管的生长极限在15min左右,然后生长变得缓慢,纳米碳管的一般长度在5~30μm.
Acetylene cracked under normal pressure at 700-800℃ with active nanoscale cobalt particles as catalyst and carbon nanotubes were prepared on a large scale. The final product rate was above 50wt% after 10min growth, and also defects were almost nonexistent. The lengthes of the carbon nanotubes ranged from 5 to 30μm. Non-well distributed carbon on catalyst surface accelerated the nucleating process. The growing time limitation was about 15min and then growing process became slow.
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