本文从先锋电子模型出发导出了直接计算离子最大几率半径的计算公式和等电子离子接触半径的经验公式。该公式物理意义明确,计算简单,数据具有足够的准确性。
On the basis of the vanguard electron model a formula for direct calculation of the maximum ionic probability radius, R_f, has been deduced: where α_0=Boron radius; R=Rydberg constant; Z=effective nuclear charge and t=spectroscopic state corresponding to the configuration of ion.An empirical formula for the contact radius of iso-electronic ion, R_0, may be expressed by: where k and b are empirical values.These formulas are characterized by clear physical definition, simple calculation and high accuracy of the data obtained.
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