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  4. 原子转移自由基聚合及催化剂负载化研究进展

高分子材料科学与工程, 2005, 21(1): 6-10.

原子转移自由基聚合及催化剂负载化研究进展

李忠辉 1, , 张永明 2, , 刘燕刚 3, , 薛敏钊 4,

1.上海交通大学化学化工学院,上海,200030

2.上海交通大学化学化工学院,上海,200030

3.上海交通大学化学化工学院,上海,200030

4.上海交通大学化学化工学院,上海,200030

关键词： 原子转移自由基聚合 , 负载型催化剂 , 可控聚合

ADVANCES OF ATOM TRANSFER RADICAL POLYMERIATION AND IT'S IMMOBILIZED CATALYST

原子转移自由基聚合(ATRP)具有可控聚合的典型特征,自1995年来受到高分子界的广泛关注.介绍了ATRP在应用方面的研究进展;传统ATRP由于存在催化剂脱除困难等问题,制约了其工业化进程.介绍了易分离的负载型催化剂的近期研究进展.

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