研究了与5284树脂体系相匹配的2种定位胶黏剂LSG-1和LSG-2,以应用于复合材料RTM制备工艺.分析了5284树脂体系的基体树脂特性与固化工艺条件,初步确定了定位胶黏剂的配方.研究了定位胶黏剂与基体树脂的黏度特性和相容性,确定了预成型体的制备工艺.通过U型回弹、压缩回弹与金相观察分析了定位胶黏剂的定位效果及产生不同定位效果的原因.研究了加入定化胶黏剂预成型体的渗透特性及其复合材料制件的力学性能.结果表明,LSG型定位胶黏剂与树脂基体匹配良好,可以使预成型体获得良好的定位效果,且不影响复合材料的性能.
Two kinds of special taekifiers LSG - 1 and LSG - 2 were studied, which would be applied in resin transfer molding (RTM) technique to prepare 5284 resin composite. On the basis of analyzing the processing conditions and properties of the matrix resin, the ingredients of tackifers were preliminary determined. By testing the viscosity of the tackifier, 5284 resin and the compatibility between the tackifier and the matrix resin 5284, the processing condition was determined. The springbacks of U-shaped bending and compression were combined with the microphotograph of the distributing condition of the tackifer to investigate the shape- fixing performance of the tackifier. The preform was fabricated by using the tackifier, and the influences of tackifiers on the processing properties and mechanical performance were studied by testing permeability of preforms and mechanical properties of the composite. The results show that the tackifier has a satisfactory compatibility with the matrix resin, would not have any negative effect on the composite, and makes the preform have a favorable shape-fixing result.
参考文献
[1] | 陈祥宝.先进复合材料低成本技术[M].北京:化学工业出版社,2004:99-155. |
[2] | 张玉龙.先进复合材料制造技术手册[M].北京:机械工业出版社,2003:337-362. |
[3] | 张彦飞,刘亚青,杜瑞奎.复合材料液体模塑成型中纤维预成型体制备技术进展[J].工程塑料应用,2006,34(8):71-74.Zhang Yanfei,Liu Yaqing,Du Ruikui.Advance of tackified fiber preform preparation in liquid composite molding technology[J].Engineering Plastics Application,2006,34(8):74-74. |
[4] | 乌云其其格,益小苏.复合材料低成本成型用预成型体的制备[J].高科技纤维与应用,2005,30(1):28-34.Wuyun Qiqige,Yi Xiaosu.Preparation of the perform for low-cost forming of composite[J].Hi-Tech Fiber & Application,2005,30(1):28-34. |
[5] | Rohatgi Vivek,Lee L James.Moldability of tackified fiber preforms in liquid composite molding[J].Journal of Composite Materials,1997,31(7):720-743. |
[6] | Tanoglu Metin,Robert S,Heider D,et al.Effects of thermoplastic preforming binder on the properties of S2-glass fabric reinforced epoxy composites[J].International Journal of Adhesion & Adhesives,2001,21:187-195. |
[7] | Tanoglu Metin,Seyhan A Tugrul.Investigating the effects of a polyester preforming binder on the mechanical and ballistic performance of E-glass fiber reinforced polyester composites[J].International Journal of Adhesion & Adhesives,2003,23(1):1-8. |
[8] | Tanoglu Metin,Seyhan A Tugrul.Compressive mechanical behaviour of E-glass/polyester composite laminates tailored with a thermoplastic preforming binder[J].Materials Science and Engineering A,2003,363(1/2):335-344. |
[9] | 梁子青,唐邦铭,李艳亮,益小苏.定型剂与树脂基体相容性研究[J].材料工程,2005(4):15-17.Liang Ziqing,Tang Bangming,Li Yanliang,Yi Xiaosu.Research on compatibility of tackifier and resing[J].Materials Engineering,2005(4):15-17. |
[10] | 张宗科.RTM工艺预成型体技术研究[D].北京:北京航空航天大学,2001. |
[11] | 乌云其其格,益小苏.一种中温定型剂及其RTM预制体性能[J].材料工程,2006(3):37-39;43.Wuyunqiqige,Yi Xiaosu.A Medium-temperature tackifier and tackification behavior[J].Materials Engineering,2006 (3):37-39; 43. |
[12] | 廖勇波,梁子青,李玲.定型剂对复合材料力学性能的影响[J].化工新型材料,2006,34(10):62-65.Liao Yongbo,Liang Ziqing,Li Ling.Resarching that tackifier A was how to affecting the mechanical performance of composites[J].New Chemical Materials,2006,34(10):62-65. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%