Infiltration-in situ reaction synthesis of C_f/TiAl_3 composite was investigated. The as-cast material was obtained by titanium particles, carbon fibers and pure aluminum. Titanium particles and carbon fibers were mixed and pressed to form a preform firstly, and then molten pure aluminum was pressed into the preform, subsequently, cooled rapidly. In situ reaction samples were obtained by heating the as-cast material from 600 to 1000℃ for 1 h. The microstructural evolution of in situ reaction samples was analyzed by scanning electron microscopy and energy dispersive X-ray. In addition, the phase composition of products was inspected by X-ray diffraction. Experimental results showed that the dominant product of TiAl_3 and a small amount of Al_4C_3 were formed at low temperature. While TiAl_3 was not stable at high temperature, along with its decrease, TiC phase became favorable. In the final products, TiAl_3, TiC and Al_4C_3 were detected. Thus, the in situ reaction for Ti-Al-C system composite proceeded a formed-decomposed- precipitated mechanism.
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