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聚丙烯纳米复合(PPNC)超短纤维表面疏水,利用2-甲基-2丙烯酰胺丙磺酸(AMPS)对其进行表面接枝。采用红外光谱(FT-IR)和扫描电镜(SEM)对超短纤维的改性效果进行表征,接触角测试研究改性超短纤维的润湿性。结果表明:接枝反应的优化条件为0.3%过氧化二异丙苯(DCP),4.0%AMPS,反应时间7h,反应温度125℃。该接枝改性样品的动态接触角降低44.20%,亲水性显著提高,更易在液相体系中分散,可开拓PPNC超短纤维混合钻井液基浆进行储层保护的应用空间。

Polypropylene nanocomposite (PPNC) super short fiber has strong hydrophobicity. The grafting copolymerization of 2-acrylamido-2- methyl propane sulfonic acid (AMPS) onto PPNC short fiber was studied. Fourier transform infrared spectra(FT-IR), scanning electron microscope (SEM) and contact angle measurements were used to characterize the modified fibers. The results show that the optimum re, action conditions are as follows: dicumyt peroxide (DCP) at 0.3%, AMPS at 4.0%, reaction time for 7 h and temperature at 125℃;. The dynamic contact angle test shows that the grafting-modified fibers poasess good hydrophilicity and dispersion in water phase, and their contact angle decreases by 44.20 %. This provides a PPNC fiber to be widely applied in the field of reservoir protection, mixed in drilling fluids.

参考文献

[1] Anton Marcincin .Modification of fiber-forming polymers by additives[J].Progress in Polymer Science,2002(5):853-913.
[2] 柯扬船,杨莉,王玉国.聚丙烯超短复合纤维的制备与性能[J].高分子材料科学与工程,2010(12):141-143.
[3] 王留阳,吕文华,方建波,陶国良.PP熔融接枝AMPS的研究[J].塑料科技,2009(04):43-46.
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