对铸造Mg-5Zn-0.6Zr-1RE-2Y镁合金进行450℃固溶+100℃时效处理,时效时间0~5个月,并通过显微硬度测试、XRD、光学金相、SEM、EDS等方法对合金时效过程中的合金相和显微组织的演变进行了研究.结果表明,450℃×12 h固溶和100℃时效后,合金随时效时间延长,晶内时效硬化效应增强,100℃时效3个月时达到硬化峰值87 HV.时效初期时合金晶内析出W相,随着时效时间的延长,合金晶内形成长周期结构X(Mg12 YZn)相,并析出β'1(MgZn)相,且含量逐渐增多.长周期X(Mg12 YZn)相和细小针(棒)状的β'1(Mgzn)相的形成是Mg-5Zn-0.6Zr-1RE-2Y合金低温时效强化的两个主要来源.
参考文献
[1] | E. Abe;Y. Kawamura;K. Hayashi .Long-period ordered structure in a high-strength nanocrystalline Mg-1 at percent Zn-2 at percent Y alloy studied by atomic-resolution Z-contrast STEM[J].Acta materialia,2002(15):3845-3857. |
[2] | T. Itoi;T. Seimiya;Y. Kawamura;M. Hirohashi .Long period stacking structures observed in Mg_(97)Zn_1Y_2 alloy[J].Scripta materialia,2004(2):107-111. |
[3] | Luo ZP.;Zhang SQ. .High-resolution electron microscopy on the X-Mg12ZnY phase in a high strength Mg-Zn-Zr-Y magnesium alloy[J].Journal of Materials Science Letters,2000(9):813-815. |
[4] | Rao JC;Song M;Furuya K;Yoshimoto S;Yamasaki M;Kawamura Y .TEM study of Mg-Zn precipitates in Mg-Zn-Y alloys[J].Journal of Materials Science,2006(9):2573-2576. |
[5] | 史菲,郭学锋,张忠明.Mg74Zn25Y1三元合金中的准晶相[J].机械工程学报,2003(08):138-140. |
[6] | Alok Singh;A.P. Tsai .On the cubic W phase and its relationship to the icosahedral phase in Mg-Zn-Y alloys[J].Scripta materialia,2003(2):143-148. |
[7] | M. Nishida;Y. Kawamura;T. Yamamuro .Formation process of unique microstructure in rapidly solidified Mg_(97)Zn_1Y_2 alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2004(0):1217-1223. |
[8] | 冯娟妮,郭学锋,徐春杰,张忠明.Mg-Zn-Y系合金的铸态组织及其相变点[J].中国稀土学报,2006(01):86-90. |
[9] | Takaomi Itoi;Tomohiro Seimiya;Yoshihito Kawamura .Microstructure of High Strength Mg_(97)Zn_1Y_2 Alloys Prepared by Extrusion of Gas-Atomized Powder[J].Materials Science Forum,2003(Pt.2):721-726. |
[10] | D. H. Bae;S. H. Kim;W. T. Kim .High Strength Mg-Zn-Y Alloy Containing Quasicrystalline Particles[J].Materials transactions,2001(10):2144-2147. |
[11] | Zhang Z M;Xu C J;Guo X F .Microatructure of Mg-6.4Zn-1-1Y alloy fabricated by rapid solidification and reciprocating extrusion[J].Acta Mathematicae Applicatae Sinica,2008,21(01):30-36. |
[12] | Garoes G;Maeso M;Todd I et al.Deformation behaviour in rapidly solidified Mg97Y2Zn(at%)alloy[J].Journal of Alloys and Compounds,2007,432:L10-L14. |
[13] | 付建强,孙威,谢中柱,刘林林,张泽.合金元素对铸态镁合金中长周期堆垛结构的形成与特征的影响[J].金属学报,2008(04):428-432. |
[14] | Buha, J .Mechanical properties of naturally aged Mg-Zn-Cu-Mn alloy[J].Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processing,2008(1/2):127-137. |
[15] | Buha J .The effect of Ba on the microstrueture and age hardening of an Mg-Zn alloy[J].Materials Science and Engineering A,2008,491(1-2):70-79. |
[16] | Buha J .The effect of micro-alloying addition of Cr on age hardening of an Mg-Zn alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2008(1/2):293-299. |
[17] | Buha J .Characterization of precipitates in an aged Mg-Zn-Ti alloy[J].Journal of Alloys and Compounds,2009,472(1-2):171-177. |
[18] | 吴安如,夏长清,王银娜,戴晓元.ZK60-xY合金的微观组织和力学性能研究[J].矿冶工程,2006(01):77-80. |
[19] | Suzuki M.;Inoue R. .Effects of Yttrium on Creep Behavior and Deformation Substructures of Magnesium[J].Materials Science Forum,2000(0):151-156. |
[20] | Maeng D.Y.;Kim T.S. .MICROSTRUCTURE AND STRENGTH OF RAPIDLY SOLIDIFIED AND EXTRUDED Mg-Zn ALLOYS[J].Scripta materialia,2000(5):358-389. |
[21] | T. Itoi;T. Seimiya;Y. Kawamura;M. Hirohashi .Long period stacking structures observed in Mg_(97)Zn_1Y_2 alloy[J].Scripta materialia,2004(2):107-111. |
[22] | Luo ZP.;Zhang SQ. .High-resolution electron microscopy on the X-Mg12ZnY phase in a high strength Mg-Zn-Zr-Y magnesium alloy[J].Journal of Materials Science Letters,2000(9):813-815. |
[23] | Rao JC;Song M;Furuya K;Yoshimoto S;Yamasaki M;Kawamura Y .TEM study of Mg-Zn precipitates in Mg-Zn-Y alloys[J].Journal of Materials Science,2006(9):2573-2576. |
[24] | Jiancun Rao;Yu Zhou;Shintaro Yoshimoto;Michioki Yomasoki;Yoshihito Kawomura .HRTEM Study of Precipitates in Mg-Zn-Y Alloys as Cast and after Extrusion[J].Advanced Engineering Materials,2005(7):610-612. |
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