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中国材料进展, 2011, 30(6): 37-43.

钛金属新型冶金技术

朱鸿民 1, , 焦树强 2, , 宁晓辉 3,

1.北京科技大学冶金与生态工程学院，北京100086

2.北京科技大学冶金与生态工程学院，北京100086

3.北京科技大学冶金与生态工程学院，北京100086

基金项目:   国家自然科学基金重点基金(50934001)   教育部长江学者和创新团队发展计划(IRT0708)  

关键词： 钛及钛合金 , 冶金技术 , 金属热还原 , 熔盐电解

New Metallurgical Technologies of Titanium Metal

尽管金属钛及其合金具有非常优异的机械性能,很强的耐腐蚀性能和耐高温性能,而且钛的矿藏资源在地球上也非常丰富,但全球金属钛的产量不到原铝产量的1％,也不到钛白粉产量的1/10.造成这一现象的主要原因是现行的钛金属生产方式,Kroll法的成本过高.在过去的几十年里,数十种新型的钛金属生产方式被提出,包括新的金属热还原,氯化物电解,氧化物熔体电解,氧化物固体电解以及复合阳极电解的方式.对上述新型钛生产工艺进行简要介绍.

参考文献

[1] 杨遇春.钛--跨入新千年的金属巨人[J].中国工程科学,2002(03):21-31.
[2] Boyer R;Welsch G;Collings E W.Materials Properties Handbook:Titanium Alloys Materials[M].Park OH:ASM Internationals,1994
[3] 王向东,郝斌,逯福生,贾翃,马云风.钛的基本性质、应用及我国钛工业概况[J].钛工业进展,2004(01):6-10.
[4] 白木,周洁.金属钛的性能、发展与应用[J].矿业快报,2003(05):1-7.
[5] 邓炬.钛与航空[J].钛工业进展,2004(02):6-15.
[6] 朱峰,张杰,李宝成,朱波,朱涛.Ti的新天地--民用钛的开发与前景[J].世界有色金属,2001(04):32-35.
[7] Joseph R. Pickens .LOW-COST Titanium for ships and tanks[J].Advanced Materials & Processes,2004(5):37-39.
[8] 杨世杰.钛在氯碱工业中的发展[J].钛工业进展,2003(04):98-100.
[9] 杨世杰.钛在纯碱工业中的应用[J].钛工业进展,2003(04):95-97.
[10] 余存烨.钛在上海石化的应用[J].钛工业进展,2003(04):116-119.
[11] 冯继承.汽车的高性能化和钛合金的应用[J].国外金属热处理,2004(02):48-51.
[12] F. H. Froes .How to Market Titanium: Lower the Cost[J].JOM,2004(2):39-0.
[13] F. H. Froes;H. Friedrich;J. Kiese .Titanium in the Family Automobile: The Cost Challenge[J].JOM,2004(2):40-44.
[14] E. B. Taddei;V. A. R. Henriques;C. R. M. Silva;C. A. A. Cairo .Production of new titanium alloy for orthopedic implants[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2004(5):683-687.
[15] The Global Titanium Industry: Review and Forecast[J].JOM,2004(11):16-0.
[16] 杨英惠.钛在体育器材及医疗器械方面的应用[J].现代材料动态,2003(02):10-12.
[17] F.H.(Sam) Froes .The Titanium Image: Bouncing Back[J].JOM,2001(4):26-0.
[18] F. H. Froes .The Titanium Image: Facing the Realities of Life[J].JOM,2000(5):12-0.
[19] K.Faller;F.H.(Sam) Froes .The Use of Titanium in Family Automobiles: Current Trends[J].JOM,2001(4):27-28.
[20] F. H. Froes;R. H. Jones .The 14th international Ti applications conference and exhibition[J].JOM,1999(6):40-41.
[21] F. H. Froes .Titanium and other light metals: let's do something about cost[J].JOM,1998(9):15-0.
[22] Kroll W J .The Production of Ductile Titanium[J].Transactions of the Electrochemical Society,1940,78:35-47.
[23] Hunter M A .Metallic Titanium:Rensselaer Polytechnic Institute Engineering[J].Journal of the American Chemical Society,1910,32:330-336.
[24] International Titanium Powder (ITP) .The Armstrong Process[EB/OL].http://www.itponline.com/,2000.
[25] Grant Crowley .How to Extract LOW-COST TITANIUM[J].Advanced Materials & Processes,2003(11):25-27.
[26] International Titanium Powder LLC .Armstrong Process[EB/OL].http://www.itponline.com/index files /Armstrong,pdf,2005.
[27] Jane W Adams;Walter N Roy;Moxson V S.Low Cost Titanium Components for Armor and Structural Applications[A].Scottsdale:AR,2005:23-27.
[28] Steven J. Gerdemann .TITANIUM Process Technologies[J].Advanced Materials & Processes,2001(7):41-43.
[29] Kraft E H .Summary of Emerging Titanium Cost Reduction Technologies.A Study Performed for US Department of Energy and Oak Ridge National Laboratory[EB/OL].http://engine-materials.oml.gov/Kraft-Titanium-2.pdf,2004-1.
[30] Okabe T H;Oda T;Mitsuda Y .Titanium Powder by Preform Reduction Process (PRP)[J].Journal of Alloys and Compounds,2004,364:156-163.
[31] Okabe T H;Oda T;Mitsuda Y.Titanium Powder Production by Preform Reduction Process[A].Weinheim:Wiley-VCH,2003:261-268.
[32] Ginatta M V .Plant for the Electrolytic Production of Reactive Metals in Molten Salt Baths[P].US,N4670121,1987-06-02.
[33] Ginatta M V .Method and Cell for the Electrolytic Production of a Polyvalent Metal[P].US,N5015342,1991-05-14.
[34] Ginatta M V.Economics and Production of Primary Titanium by Electrolytic Winning[A].TMS,2001:13-27.
[35] Takenaka T;Suzuki T;Ishikawa M et al.The New Concept of Electrowinning Process of Liquitd Titanium Metal in Molten Salt[J].Electroanalytical Chemistry,1999,67:661-668.
[36] Cardarelli F .A Method for Electrowinning of Titanium or Alloy fror Titanium Oxide Containing Compound in the Liquid State[P].International Pat:WO 03046258,2003.
[37] Sadoway DR. .NEW OPPORTUNITIES FOR METALS EXTRACTION AND WASTE TREATMENT BY ELECTROCHEMICAL PROCESSING IN MOLTEN SALTS[J].Journal of Materials Research,1995(3):487-492.
[38] Published by MIT .A Cleaner,Cheaper Route to Titanium[EB/OL].http://www.technologyreview.com/business/16963,2006.
[39] Chen G Z;Fray D J;Farthing T W .Direct Electrochemical Reduction of Titanium Dioxide to Titanium in Molten Calcium Chloride[J].Nature,2000,407:361-364.
[40] Derek J. Fray .Emerging molten salt technologies for metals production[J].JOM,2001(10):26-31.
[41] Chen G Z;Fray D J.Electro-Deoxidation of Metal Oxides[J].Light Metals,2001:1147-1151.
[42] Chen G Z;Fray D J;Farthing T W .Cathodic Deoxygenation of the Alpha-Case on Titanium and Alloys in Molten Calcium Chloride[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,2001,36:720,1041.
[43] Ginatta Marco Vincenzo .Process for the Electrolytic Production of Metals[P].US,6074545,2000-07-13.
[44] Katsutoshi Ono;Ryosuke O. Suzuki .A New Concept for Producing Ti Sponge: Calciothermic Reduction[J].JOM,2002(2):59-61.
[45] Suzuki R O;Ono K O S.Process-Thermochemical Approach to Reduce Titanium Oxide in the Molten Salt CaCl2[A].Warrendale:TMS Press,2003:187-199.
[46] RYOSUKE O. SUZUKI;KOH TERANUMA;KATSUTOSRI ONO .Calciothermic Reduction of Titanium Oxide and in-situ Electrolysis in Molten CaCl_2[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2003(3):287-295.
[47] RYOSUKE O. SUZUKI;SHUICHI INOUE .Calciothermic Reduction of Titanium Oxide in Molten CaCl_2[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2003(3):277-285.
[48] Wainer E .Cell Feed Material for the Production of Titanium[P].US,2868703,1959-01-13.
[49] Wainer E;Heights C Ohio .Thermal and Electrochemical Process for Metal Production[P].US,2722509,1955.
[50] 竹内泶;渡辺治 .TiO,TiCおよびTi-C-O合金またはを陽極からのTi電解抽出に関する研究[J].日本金属学会志(日本),1964,28:627-632.
[51] 橋本雍彦 .Ti-C-O合金またはTiCを陽極とするTiの溶融墟電解[J].日本金属学会志(日本),1968,32:1327-1333.
[52] 橋本雍彦 .チ夕ンの溶融墟電解製鍊における低品位可溶性陽極よりのチタンの陽極の溶出[J].日本金属学会志(日本),1971,35:480-486.
[53] Withers J;Laughlin J;Loutfy R O.Innovations in Titanium Technology[M].Warrendale,PA:TMS,2007:117-126.
[54] Withers J.International Round Table on Titanium Production in Molten Salts[M].Cologne Germany,2008:70-74.
[55] Shuqiang Jiao;Hongmin Zhu .Novel metallurgical process for titanium production[J].Journal of Materials Research,2006(9):2172-2175.
[56] Shuqiang Jiao;Hongmin Zhu .Electrolysis of Ti_2CO solid solution prepared by TiC and TiO_2[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2007(1/2):243-246.
[57] 朱鸿民;焦树强;顾学范 .一氧化钛/碳化钛可溶性固溶体阳极电解生产纯钛的方法[P].China,200510011684.6,2005-05-08.
[58] Jiao, S.;Ning, X.;Huang, K.;Zhu, H. .Electrochemical dissolution behavior of conductive TiC_xO _(1-x) solid solutions[J].Pure and Applied Chemistry,2010(8):1691-1699.
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