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利用扫描电镜(SEM)、X射线光电子谱(XPS)、X射线衍射(XRD)分析以及电化学实验研究了乙醇胺(ETA)浓度对碳钢和690合金浸泡腐蚀和电化学腐蚀行为的影响.结果表明,碳钢的点蚀随着浓度的增加明显减少,碳钢表面腐蚀产物的主要成分为Fe3O4,690合金表面膜中没有观察到双层膜结构;在浓度为40、50、80 mg/L时观察到Cr的富集峰.在280℃条件下的电化学实验结果表明,ETA浓度为20 mg/L和40 mg/L时,对碳钢和690合金的电化学腐蚀行为影响不大.而在80 mg/L时,两种材料的腐蚀电流密度下降较多,极化电阻显著增大.

参考文献

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[3] Wenjun Kuang;Xinqiang Wu;En-Hou Han;Jiancun Rao .The mechanism of oxide film formation on Alloy 690 in oxygenated high temperature water[J].Corrosion Science,2011(11):3853-3860.
[4] A. Machet;A. Galtayries;S. Zanna;L. Klein;V. Maurice;P. Jolivet;M. Foucault;P. Combrade;P. Scott;P. Marcus .XPS and STM study of the growth and structure of passive films in high temperature water on a nickel-base alloy[J].Electrochimica Acta,2004(22/23):3957-3964.
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