采用正交实验法和金相、力学性能、扫描电镜、能谱等测试手段对自主研发的变形Al-Si-Cu-Mg合金进行固溶和时效强化研究,并探究热处理过程中其组织特征的变化规律.结果表明:通过固溶(495℃,90 min,水冷)和时效(170℃,4h,空冷)处理后,合金的硬度提高31.3%,强度提高3.3倍.固溶过程中,大量Si、Cu和Mg原子固溶于基体中,起到强烈的固溶强化作用;过剩的共晶Si逐渐发生明显粒状化;剩余的大块θ相和Q相发生球化.时效过程中,细小针状强化相θ”和细小板条状Q'相在基体的(100)面上大量析出,分布均匀,对合金起到强烈的沉淀强化效果;过剩Si主要通过扩散附着于共晶Si表面析出.
参考文献
[1] | A.M.A. Mohamed;F.H. Samuel;A.M. Samuel;H.W. Doty .Influence of additives on the impact toughness of Al-10.8% Si near-eutectic cast alloys[J].Materials & design,2009(10):4126-4135. |
[2] | Fangtao Xu;Yuan Xia;Guang Li .The mechanism of PEO process on Al-Si alloys with the bulk primary silicon[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(23):9305-9310. |
[3] | 李润霞 .高强度铸造Al-Si-Cu-Mg合金固态相变研究[D].沈阳工业大学,2004. |
[4] | 祖方遒.变质元素对铸造Al-Si合金共晶结晶的作用及机制[J].铸造,2011(11):1073-1079. |
[5] | 王明杰.铝-硅合金砂型铸件改为压铸生产的工艺改进[J].轻合金加工技术,2006(11):9-12. |
[6] | 黄正军 .铸造AlSi7Cu2Mg合金成分优化及组织、性能研究[D].中北大学,2009. |
[7] | 姚书芳.铸造铝硅合金细化变质处理的研究进展[J].铸造,2000(09):512. |
[8] | ZEREN M;KARAKULAK E .Study on hardness and microstructure characteristics of sand cast Al-Si-Cu alloys[J].Bulletin of Materials Science,2009,32(06):617-620. |
[9] | Tavitas-Medrano, FJ;Mohamed, AMA;Gruzleski, JE;Samuel, FH;Doty, HW .Precipitation-hardening in cast AL-Si-Cu-Mg alloys[J].Journal of Materials Science,2010(3):641-651. |
[10] | S.K. CHAUDHURY;D. APELIAN .Fluidized Bed Heat Treatment of Cast Al-Si-Cu-Mg Alloys[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2006(7):2295-2311. |
[11] | Samuel FH. .Incipient melting of Al5Mg8Si6Cu2 and Al2Cu intermetallics in unmodified and strontium-modified Al-Si-Cu-Mg (319) alloys during solution heat treatment[J].Journal of Materials Science,1998(9):2283-2297. |
[12] | 杨明波,代兵,钱翰城.高强韧铸造铝硅合金Al-7%Si-1.5%Cu-Mg-Ti-Mn最佳热处理工艺的研究[J].铸造,2002(08):470-473. |
[13] | Ott RD.;Santella ML.;Blau PJ.;Blue CA. .The influence of a heat treatment on the tribological performance of a high wear resistant high SiAl-Si alloy weld overlay[J].Wear: an International Journal on the Science and Technology of Friction, Lubrication and Wear,2001(2):868-874. |
[14] | BASSAI P;GARIBOLDI E;VINERCATI G .Calorimetric analysis on aged Al-4.4Cu-0.5Mg-0.9Si-0.8Mn alloy[J].Journal of Thermal Analysis and Calorimetry,2007,87(01):247-253. |
[15] | D. J. Chakrabarti;David E. Laughlin .Phase relations and precipitation in Al-Mg-Si alloys with Cu additions[J].Progress in materials science,2004(3/4):389-410. |
[16] | ARNBERG L;AURIVILLIUS B .The crystal structure of AlxCu2Mg12-xSi7,(h-AlCuMgSi)[J].Acta Chemica Scandinavica,1980,34:1-5. |
[17] | RAVI C;WOLVERTON C .First-principle study of crystal structure and stability of Al-Mg-Si-(Cu) precipitates[J].Acta Materialia,2004,52:4213-4227. |
[18] | R.X. Li;R.D. Li;Y.H. Zhao;L.Z. He;C.X. Li;H.R. Guan;Z.Q. Hu .Age-hardening behavior of cast Al-Si base alloy[J].Materials Letters,2004(15):2096-2101. |
[19] | G.C. WEATHERLY;A. PEROVIC;N.K. MUKHOPADHYAY .The Precipitation of the Q Phase in an AA6111 Alloy[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2001(2):213-218. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%