材料期刊网

本文提出一种新方法,从现有活度实验数据求得Fe-C合金奥氏体和铁素体中C-C交互作用能,碳的偏摩尔焓和偏摩尔非配置熵.将这些数据用于计算Fe-C相图,平衡部分结果与实测相图十分符合.同过去的方法相比较,本文方法能从分散、有限的活度实验数据中得到更合理的结果.然而分析表明,迄今碳在铁素体中活度数据仍欠精确,尚难依据它来确定具有明确物理意义的铁素体中C-C交互作用能数值。

A new approach has been suggested for the determination of the C-C interaction energy, the partial molar enthalpy and nonconfigurational entropy of carbon in the Fe-C austenite and ferrite from available activity data. By application of the values obtained through the approach to the calculation of the Fe-C phase diagram, the results in the equilibrium region are in very good agreement with the experimental one. From the scattered and limited experimental activity data, the C-C interaction energy obtained through the present approach should be more reasonable than that through previous efforts. Further analysis indicates, however, that up to now the activity data on carbon in ferrite are not accurate enough for obtaining the C-C interaction energy in ferrite with the clear physical significance.