Polycrystalline SnO2 thin films were deposited on sapphire substrates at 450℃ under different ambient oxygen pressures by pulsed laser deposition technique. The effect of ambient oxygen pressure on the structural, optical and electrical properties of SnO2 thin films was studied. X-ray diffraction and Hall measurements show that increasing the ambient oxygen pressure can improve crystallization of the films and decrease resistivity of the films. A violet emission peak centered at 409 nm was observed from photoluminescence measurements for SnO2 films under deposition ambient oxygen pressure above 5 Pa, which is related to the improvement of crystalline of the films.
参考文献
[1] | Dolbec R.;El Khakani MA.;Serventi AM.;Trudeau M.;Saint-Jacques RG. .Microstructure and physical properties of nanostructured tin oxide thin films grown by means of pulsed laser deposition[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2002(1/2):230-236. |
[2] | Yang Huaming,Zhang Xiangchao,YANG Wuguo,HUANG Chenghuan,Qiu Guanzhou.Chemical synthesis of nanocrystalline ZrO2-SnO2 composite powders[J].稀有金属(英文版),2004(02):182-184. |
[3] | Schmid W.;Barsan N.;Weimar U. .Sensing of hydrocarbons with tin oxide sensors: possible reaction path as revealed by consumption measurements[J].Sensors and Actuators, B. Chemical,2003(3):232-236. |
[4] | Chopra K L;Major S;Pandya D K .Transparent conductors-A status review[J].Thin Solis Films,1983,102(01):1. |
[5] | Abass A K;Mohammad M T .Optical properties of fluorine-doped SnO2 films[J].Journal of Applied Physics,1986,59:1641. |
[6] | Zhang Xiangjun,Huang Songtao,Wu Guoliang,Lu Shigang,CAI Zhenping.Tin oxide-graphite composite for lithium storage material in lithium-ion batteries[J].稀有金属(英文版),2003(03):226-229. |
[7] | Lee SC.;Lee JH.;Oh TS.;Kim YH. .Fabrication of tin oxide film by sol-gel method for photovoltaic solar cell system[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2003(3/4):481-487. |
[8] | Bruno L;Pijolat C;Lalauze R .Tin dioxide thin-film gas sensor prepared by chemical vapour deposition:Influence of grain size and thickness on the electrical properties[J].Sensors and Actuators B:Chemical,1994,18(01):195. |
[9] | Dieguez A;Romano-Rodriguez A;Morante J R;Kappler J, Barsan N, Gopel W .Nanoparticle engineering for gas sensor optimisation:improved sol-gel fabricated nanocrystalline SnO2 thick film gas sensor for NO2 detection by calcination,catalytic metal introduction and grinding treatments[J].Sensors and Actuators B:Chemical,1999,60(01):125. |
[10] | Cricenti A.;Scarselli MA.;Perfetti P.;Siciliano P.;Serra A.;Tepore A.;Coluzza C.;Almeida J.;Margaritondo G.;Generosi R. .MORPHOLOGICAL, CHEMICAL AND ELECTRICAL CHARACTERIZATION OF PT-SNO2 THIN FILM GROWN ON ROUGH AND MECHANICALLY POLISHED AL2O3 SUBSTRATES[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,1996(9):2235-2239. |
[11] | Chrisey D B;Hubler G K.Pulsed Laser Deposition of Thin Films[M].New York:John Wiley and Sons,1994:393. |
[12] | Hu W S;Liu Z G;Zheng J G;Hu W B, Guo X L, Gopel W .Preparation of nanocrystalline SnO2 thin films used in chemisorption sensors by pulsed laser reactive ablation[J].J Mater Sci Mater Electron,1997,8(01):155. |
[13] | Vispute R D;Godbole V P;Chaudhari S M;Kanetkar S M, Ogale S B .Deposition of tin oxide films by pulsed laser evaporation[J].Journal of Materials Research,1988,3(06):1180. |
[14] | Feng J;Jin M;Wang Y H;Ma H L, Yu X H, Zong F J .Photoluminescence of SnO2 films prepared by APCVD[J].Mate Sci Forum,2005,475-479:3701. |
[15] | Kim T W;Lee D U;Yoon Y S .Microstrucrural,electrical,and optical properties of SnO2nanocrystalline thin films grown on InP (100) substrates for applications as gas sensor devices[J].Journal of Applied Physics,2000,88(06):3759. |
[16] | Jeong J.;Choi SP.;Chang CI.;Shin DC.;Park JS.;Lee BT.;Park YJ.;Song HJ. .Photoluminescence properties of SnO2 thin films grown by thermal CVD[J].Solid State Communications,2003(9/10):595-597. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%