对具有临界相行为(LCST、UCST)的聚合物共混体系,小应变状态下的动态流变行为对体系在相分离过程中形态结构的形成与演化极其敏感,非均相结构的产生使体系在长时松弛区域表现出与均相聚合物体系不同的粘弹松弛行为,即弹性显著增加、松弛时间明显增长以及时-温叠加原理失效,偏离经典的线性粘弹理论模型.这为用动态流变学方法研究聚合物共混体系的相行为提供了理论依据.文中综述了该领域的研究进展.
参考文献
| [1] | Gennes P G J .[J].Chemical Physics,1980,72:4756. |
| [2] | HanCD;Kim J K .[J].Polymer,1993,34:2533. |
| [3] | Kapnistos M.;Vlassopoulos D.;Anastasiadis SH.;Stammer A. Wolf BA.;Hinrichs A. .RHEOLOGY OF A LOWER CRITICAL SOLUTION TEMPERATURE BINARY POLYMER BLEND IN THE HOMOGENEOUS, PHASE-SEPARATED, AND TRANSITIONAL REGIMES[J].Macromolecules,1996(22):7155-7163. |
| [4] | Kapnistos M;Vlassopoulos D;Anastasiadis S H .[J].EUROPHYSICS LETTERS,1996,34:513. |
| [5] | Vlassopoulos D .[J].Rheologica Acta,1996,35:556. |
| [6] | Kim JK.;Son HW.;Han CD.;Lee HH. .Phase behavior and rheology of polystyrene/poly(alpha-methylstyrene) and polystyrene poly(vinyl methyl ether) blend systems[J].Macromolecules,1998(24):8566-8578. |
| [7] | Zheng Q.;Yang BB.;Wu G.;Du M. .Relationship between dynamic theological behavior and phase separation of poly(methyl methacrylate)/poly(styrene-co-acrylonitrile) blends[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(13):5743-5747. |
| [8] | Utracki L A.Polymer Alloys and Blends[M].New York: Carl Hanser,1989:131. |
| [9] | Yanovsky Y G.Polymer Rheology: Theory and Practice[M].London: Chapman & Hall,1993:112. |
| [10] | Ferry J D.Viscoelastic Properties of Polymers[M].New York:wiley,1980:56. |
| [11] | Ajji A;Prud′homme R E .[J].Journal of Polymer Science Part B:Polymer Physics,1988,26:2279. |
| [12] | Mani S;Malone M F;Winter H H .[J].Journal of Rheumatology,1992,36:1625. |
| [13] | Brekner M;Cantow H;Schneider H .[J].POLYMER BULLETIN,1985,14:17. |
| [14] | Yang H H;Han C D;Kim J K .[J].Polymer,1994,35:1503. |
| [15] | Friedrich C.;Riemann RE.;Schwarzwalder C. .RHEOLOGICAL AND THERMODYNAMIC STUDY OF THE MISCIBLE BLEND POLYSTYRENE/POLY(CYCLOHEXYL METHACRYLATE)[J].Polymer: The International Journal for the Science and Technology of Polymers,1996(12):2499-2507. |
| [16] | Aoki Y;Tanaka T .[J].Macromolecules,1999,32:8560. |
| [17] | 郑强,荒木修,升田利史郎.用动态粘弹函数关系表征PMMA/α-MSAN共混物的相分离[J].高等学校化学学报,1998(08):1339-1342. |
| [18] | 郑强,高桥雅兴,升田利史郎.PMMA/α-MSAN共混体系长时弛豫区域的时温叠加失效与相分离的关系[J].高等学校化学学报,1999(06):969-973. |
| [19] | Chopra D.;Kontopoulou M.;Vlassopoulos D.;Hatzikiriakos SG. .Effect of maleic anhydride content on the rheology and phase behavior of poly(styrene-co-maleic anhydride)/poly(methyl methacrylate) blends[J].Rheologica Acta: An International Journal of Rheology,2002(1/2):10-24. |
| [20] | Chopra D;Vlassopoulos D .[J].Journal of Rheumatology,1998,42:1227. |
| [21] | Jeon H S;Nakatani A I;Han C C et al.[J].Macromolecules,2000,33:9732. |
| [22] | Nesarikar AR. .RHEOLOGY OF POLYMER BLEND LIQUID-LIQUID PHASE SEPARATION[J].Macromolecules,1995(21):7202-7207. |
| [23] | Vlassopoulos D;Koumoutsakos A;Anastasiadis S H .[J].Journal of Rheumatology,1997,41:739. |
| [24] | Colby R H .[J].Polymer,1989,30:1275. |
| [25] | Wu S H .[J].Polymer Science SERIES B:Polymer Physics,1987,25:2511. |
| [26] | HanCD;Kim J K .[J].Macromolecules,1989,22:4292. |
| [27] | Widmayer J M;Meyer G C .[J].Journal of Polymer Science Part B:Polymer Physics,1980,18:2217. |
| [28] | Bates F S;Hartney M A .[J].Macromolecules,1985,18:2478. |
| [29] | Fredrickson G H;Larson R G .[J].Macromolecules,1987,20:1897. |
| [30] | Palierne J F .[J].Rheologica Acta,1990,29:204. |
| [31] | Graebling D;Muller R;Palierne J F .[J].Macromolecules,1993,26:320. |
| [32] | Vinckier I;Laun H M .[J].Rheologica Acta,1999,38:274. |
| [33] | Polios IS.;Lee C.;Gido SP.;Schmidtrohr K.;Winter HH.;Soliman M. .LATE STAGES OF PHASE SEPARATION IN A BINARY POLYMER BLEND STUDIED BY RHEOLOGY, OPTICAL AND ELECTRON MICROSCOPY, AND SOLID STATE NMR[J].Macromolecules,1997(15):4470-4480. |
| [34] | Zhang Z L;Zhang H D;Yang Y L et al.[J].Macromolecules,2001,34:1416. |
| [35] | Kim J K;Son H W;Lee Y.[J].Journal of Polymer Science Part B:Polymer Physics,1999:37,889. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%