以N-甲基咪唑和溴代正丁烷为起始原料,采用两步法合成了1-丁基-3-甲基咪唑四氟硼酸盐离子液体,并对所合成的离子液体做了红外光谱表征.在1-丁基-3-甲基咪唑四氟硼酸盐离子液体中,利用硼氢化钠还原氯金酸,制备了纳米金.紫外-可见光谱和透射电镜(TEM)试验结果表明,所制备的纳米金以链状为主.离子液体在纳米金制备过程中不仅起到了溶剂作用,还起到了修饰剂的作用.
参考文献
| [1] | Wasserscheid P;Keim W .[J].Angewandte Chemie International Edition,2000,39:3772. |
| [2] | Earle M J;Seddon K R .[J].Pure and Applied Chemistry,2000,72:1391. |
| [3] | Welton T .[J].Chemical Reviews,1999,99:2071. |
| [4] | Hagiwara R;Ito Y .[J].Journal of Fluorine Chemistry,2000,105:221. |
| [5] | Olivier H .[J].Journal of Molecular Catalysis A:Chemical,1999,146:285. |
| [6] | Frens G .[J].Nature Physical Science,1973,241(105):20. |
| [7] | Glish G L;Evans N D;Murray R W et al.[J].Langmuir,1998,14(01):17. |
| [8] | Li Yadong;Wang Xun;Zhuang Jing et al.[J].NATURE,2005,437(01):121. |
| [9] | Chiang CL;Hsu MB;Lai LB .Control of nucleation and growth of gold nanoparticles in AOT/Span80/isooctane mixed reverse micelles[J].International Journal of Quantum Chemistry,2004(11):3891-3895. |
| [10] | Sau TK;Murphy CJ .Self-assembly patterns formed upon solvent evaporation of aqueous cetyltrimethylammonium bromide-coated gold nanoparticles of various shapes[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(7):2923-2929. |
| [11] | Tapan K.Sau;Catherine J.Murphy .Seeded High Yield Synthesis of Short Au Nanorods in Aqueous Solution[J].Langmuir: The ACS Journal of Surfaces and Colloids,2004(15):6414-6420. |
| [12] | Inasawa S;Sugiyama M;Koda S .Size controlled formation of gold nanoparticles using photochemical grwoth and photothermal size reduction by 308 nm laser pulses[J].Japanese journal of applied physics,2003(10):6705-6712. |
| [13] | Kenji Okitsu;Akihiko Yue;Shuji Tanabe;Hiroshige Matsumoto;Yoshihiro Yobiko .Formation of Colloidal Gold Nanoparticles in an Ultrasonic Field: Control of Rate of Gold (III) Reduction and Size of Formed Gold Particles[J].Langmuir: The ACS Journal of Surfaces and Colloids,2001(25):7717-7720. |
| [14] | Hideaki Itoh;Kensuke Naka;Yoshiki Chujo .Synthesis of Gold Nanoparticles Modified with Ionic Liquid Based on the Imidazolium Cation[J].Journal of the American Chemical Society,2004(10):3026-3027. |
| [15] | Kim Kisub;Demberelnyamba D;Lee Huen .[J].Langmuir,2004,20(03):556. |
| [16] | Bonhote P.;Papageorgiou N.;Kalyanasundaram K.;Gratzel M.;Dias AP. .HYDROPHOBIC, HIGHLY CONDUCTIVE AMBIENT-TEMPERATURE MOLTEN SALTS[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,1996(5):1168-1178. |
| [17] | Mohamed MB.;Link S.;El-Sayed MA.;Volkov V. .The 'lightning' gold nanorods: fluorescence enhancement of over a million compared to the gold metal[J].Chemical Physics Letters,2000(6):517-523. |
| [18] | Jin R C;Cao Y W;Mirkin Chad A et al.[J].Science,2002,294:1901. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%