Highly oriented ZnO nanorod arrays were suecessfully prepared on the indium tin oxide (ITO) substrate using a galvanostatic electrodeposition method.The ITO substrate was pretreated with ZnO nanoparticles via simple low-temperature solution route.The crystallinity,microstructure of surface,and optical properties of the obtained ZnO were characterized by X-ray diffraction,scanning electron microscope,and transmittance spectrum.The results indicate that the average diameter of ZnO nanorod arrays is about 30 nm,and the narrow size distribution ranges from 20 to 50 nm The nanorod arrays are growing along [001] direction with an orientation perpendicular to the substrate.When the wavelength of incident is over 380 nm,the ZnO nanorod arrays show a high optical transmission of above 95%.Furthermore,the possible growth mechanism of the nanorod arrays was discussed.
参考文献
[1] | Min Lai;D.Jason Riley .Templated Electrosynthesis of Zinc Oxide Nanorods[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(9):2233-2237. |
[2] | A. Goux;T. Pauporte;J. Chivot;D. Lincot .Temperature effects on ZnO electrodeposition[J].Electrochimica Acta,2005(11):2239-2248. |
[3] | Huang M H;Mao S;Feick H;Yah H,Wu Y,Kind H,Weber E,Russo R,and Yang P .Room-temperature ultraviolet nanowire nanolasers[J].Science,2001,292(5523):1897. |
[4] | 黄焱球,刘梅冬,曾亦可,刘少波.ZnO薄膜及其性能研究进展[J].无机材料学报,2001(03):391-397. |
[5] | Mahalingam T;John VS;Raja M;Su YK;Sebastian PJ .Electrodeposition and characterization of transparent ZnO thin films[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2005(2):227-235. |
[6] | Jr H. He;Chang S. Lao;Lih J. Chen;Dragomir Davidovic;Zhong L. Wang .Large-Scale Ni-Doped ZnO Nanowire Arrays and Electrical and Optical Properties[J].Journal of the American Chemical Society,2005(47):16376-16377. |
[7] | Subramanyam TK.;Uthanna S.;Naidu BS. .Physical properties of zinc oxide films prepared by dc reactive magnetron sputtering at different sputtering pressures[J].Crystal Research and Technology: Journal of Experimental and Industrial Crystallography,2000(10):1193-1202. |
[8] | Ataev B M;Bagamadova A M;Mamedov V V;Omaev A K .Thermally stable,highly conductive,and transparent ZnO layers prepared in situ by chemical vapor deposition[J].Materials Science and Engineering,1999,65(03):159. |
[9] | Sun X W;Kwok H S .Optical properties of epitaxially grown zinc oxide films on sapphire by pulsed laser deposition[J].Journal of Applied Physics,1999,86(01):408. |
[10] | Sun XM.;Deng ZX.;Li YD. .Self-organized growth of ZnO single crystal columns array[J].Materials Chemistry and Physics,2003(1):366-370. |
[11] | Xu L E;Guo Y;Liao Q;Zhang J P Xu D S .Morphological control of ZnO nanostructures by electrodeposition[J].Journal of Physical Chemistry B,2005,109(28):13519. |
[12] | Thierry Pauporte;Daniel Lincot .Electrodeposition of semiconductors for optoelectronic devices: results on zinc oxide[J].Electrochimica Acta,2000(20):3345-3353. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%