应用“团簇加连接原子”结构模型对镍基高温合金成分进行了解析,指出了这些合金均源自基础团簇式[Cr-Ni12]Cr3,其中[Cr-Ni12]为在FCC结构中以Cr为心的立方八面体团簇,搭配以3个Cr作为连接原子.根据合金化组元与基体Ni的混合焓大小确定其在团簇式中的位置,最终形成多元合金化后的团簇式[(Al/Ti/Nb)-(Ni/Fe/Co)12](Cr/Al)3.采用铜模吸铸快冷技术制备φ10 mm的合金棒,并对其在1373 K保温2h后空冷.结果表明团簇式中含有一个Al时会有细小的γ'相析出,含有两个Al时[Al-(Ni10Fe2)](Cr2Al)合金中γ'相球形析出,粒子尺寸为30 ～ 60 nm；硬度测试表明前者强化效果不明显,后者由于γ'粒子长大使得合金硬度提高.当Al/Ti/Nb等比例占据团簇心部时,[(Al1/3 Ti1/3 Nb1/3)-(Ni10 Fe2)]Cr3合金的硬度最高,为2.86 GPa.
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