利用XRD,SEM和EDX对石墨表面钛金属化界面的物相、微观组织及成分进行了分析.结果表明,金属化石墨微观组织呈层状结构,依次为内层(石墨)、过渡层、致密层及外层(Ti),其中过渡层厚约为720 μm,致密层厚约为40 um.XRD及EDX分析证实了致密层物相为碳化钛,SEM分析证实了致密层与过渡层及Ti层结合牢固.但还发现在Ti层与致密层界面处存在短微裂纹,在致密层与过渡层界面处未有发现,原因主要是材料间的热膨胀系数差异产生热应力所致.并且还对石墨表面金属化机理进行了探讨.研究表明,其机理是通过金属Ti与石墨发生界面反应生成碳化钛来实现.
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